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铜山矿区周边农田土壤重金属来源解析及污染评价
摘要点击 2469  全文点击 733  投稿时间:2021-08-25  修订日期:2021-10-07
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中文关键词  土壤重金属  源解析  PMF模型  物元可拓模型  毒性响应系数
英文关键词  soil heavy metals  source resolution  PMF model  matter element extension model  toxicity response coefficient
作者单位E-mail
陈航 西安理工大学西北旱区生态水利国家重点实验室, 西安 710048 2464654342@qq.com 
王颖 西安理工大学西北旱区生态水利国家重点实验室, 西安 710048 wangying@xaut.edu.cn 
王澍 河南省资源环境调查五院, 郑州 450000  
中文摘要
      为探明铜山矿区周边农田土壤重金属主要来源及污染程度,采集并测定了361个表层土壤(0~20 cm)样品重金属Ag、Cu、Pb、Zn、Mo、Sb、Ba、As和Hg.利用PMF模型和IDW插值相结合的方法对研究区土壤重金属进行来源解析及空间分布特征分析.在传统物元可拓模型的基础上,引入Hakanson毒性响应系数修正权重系数对重金属污染水平进行评价,并将评价结果与Muller指数(Igeo)和Nemerow综合指数(PN)进行对比.结果显示:① ω(Ag)、ω(Cu)、ω(Pb)、ω(Zn)、ω(Mo)、ω(Sb)、ω(Ba)、ω(As)和ω(Hg)均值分别为0.05、19.32、23.34、62.89、0.97、0.87、542.56、8.88和0.07 mg ·kg-1,其中Zn和Hg均高出河南省土壤背景值,但低于农用地土壤污染风险管制值,研究区土壤9种重金属在空间上主要呈现岛状和片状分布.②修正权重系数的物元可拓模型评价结果显示,研究区仅有6.37%的表层土壤为清洁土壤,89.75%为尚清洁,3.32%为轻度污染,0.277%为重度污染,Hg为主要的污染元素;修正权重系数的物元可拓模型评价结果与Muller指数法和Nemerow指数法结果大致相同,说明修正权重系数的物元可拓模型可用于土壤重金属污染评价,评价结果准确客观.③铜山矿区周边农田土壤重金属主要来源于农药使用和矿业开发排放混合源(18.79%),农业活动和自然母质混合源(22.02%),化石燃烧释放和农业活动混合源(15.57%),矿业开发排放源(11.06%),交通运输、自然母质和矿业开发这3个因素混合源(32.51%).
英文摘要
      In order to identify the main sources and pollution degrees of heavy metals in farmland soil around the Tongshan mining area, 361 surface soil (0-20 cm) samples were collected and measured for the heavy metals Ag, Cu, Pb, Zn, Mo, Sb, Ba, As, and Hg. The source analysis and spatial distribution characteristics of the soil heavy metals in the study area were analyzed using the combination of a PMF model and IDW interpolation. Based on the traditional matter-element extension model, the Hakanson toxicity response coefficient and modified weight coefficient were introduced to evaluate the pollution level of heavy metals, and the evaluation results were compared with those from the Muller index (Igeo) and Nemerow comprehensive index (PN). The results showed that:① the mean values of ω(Ag), ω(Cu), ω(Pb), ω(Zn), ω(Mo), ω(Sb), ω(Ba), ω(As), and ω(Hg)were 0.05, 19.32, 23.34, 62.89, 0.97, 0.87, 542.56, 8.88, and 0.07 mg·kg-1, respectively. Zn and Hg were higher than the soil background value of Henan Province but lower than the soil pollution risk control value of agricultural land. The nine heavy metals in the soil of the study area mainly showed island and sheet distribution in space. ② The evaluation results of the matter-element extension model with a modified weight coefficient showed that only 6.37% of the topsoil in the study area was previously clean soil, 89.75% was still clean, 3.32% was slightly polluted, and 0.277% was heavily polluted, and Hg was the main polluting element. The evaluation results of the matter-element extension model with the modified weight coefficient were roughly the same as those of the Muller index and Nemerow index methods, indicating that the matter-element extension model with the modified weight coefficient could be used for the evaluation of soil heavy metal pollution, and the evaluation results were accurate and objective. ③ The heavy metals in the farmland soil around the Tongshan mining area mainly came from the mixed source of pesticide use and mining development (18.79%), the mixed source of agricultural activities and natural parent material (22.02%), the mixed source of fossil combustion release and agricultural activities (15.57%), the emission source of mining development (11.06%), and the mixed source of transportation, natural parent material, and mining development (32.51%).

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