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淄博市冬季PM2.5载带金属元素污染特征、生态风险评价及来源分析
摘要点击 2076  全文点击 664  投稿时间:2021-08-28  修订日期:2021-09-26
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中文关键词  PM2.5  金属元素  地累积指数  生态风险  来源分析
英文关键词  PM2.5  metallic element  geo-accumulation index  ecological risk  source apportionment
作者单位E-mail
白雯宇 中国环境科学研究院, 北京 100012 bai.wenyu@craes.org.cn 
徐勃 山东省淄博生态环境监测中心, 淄博 255040  
郭丽瑶 中国环境科学研究院, 北京 100012  
殷宝辉 中国环境科学研究院, 北京 100012  
马银红 中国环境科学研究院, 北京 100012  
李丽明 中国环境科学研究院, 北京 100012  
杨文 中国环境科学研究院, 北京 100012  
赵雪艳 中国环境科学研究院, 北京 100012 zhaoxy@craes.org.cn 
中文摘要
      为研究淄博市城区冬季环境空气PM2.5载带金属元素的污染特征、来源和生态风险,于2019年1月8~23日在淄博市采集环境空气PM2.5滤膜样品并分析获取14种金属元素的浓度.结果表明,K含量均值为8071.6 mg ·kg-1,是含量最高的元素,但未超过山东省A层土壤背景值,说明K主要来自自然源;Zn、Pb、Cu、Cr、As、Ni和Cd等元素含量明显低于K元素(28.4~4282.3 mg ·kg-1),但均明显高于山东省A层土壤背景值,依次为背景值的56.6、19.0、7.2、2.4、7.3、1.4和283.8倍,反映出人为源的影响.地累积指数(Igeo)表明,冬季PM2.5中Cd、Zn、Pb、Cu和As受污染程度较高,均为中度污染及以上.潜在生态风险评价结果显示Cd存在极强的生态危害风险.综合运用相关性分析、富集因子法和主成分分析多种方法解析出,土壤扬尘、机动车尾气、燃煤和冶金行业是淄博市城区环境空气PM2.5载带金属元素的主要来源,需要加强这几类污染源的管控.
英文摘要
      In order to study the pollution characteristics, sources, and ecological risk of the metallic elements in ambient PM2.5 during winter in Zibo City, ambient PM2.5 samples were collected in January 2019, after which 14 types of metallic elements were investigated. The results showed that the average value of K content was 8071.6 mg·kg-1and was highest in the types of metallic elements, which was lower than that of the soil background value in Shandong province. The mean values of Zn, Pb, Cu, Cr, As, Ni, and Cd were 56.6, 19.0, 7.2, 2.4, 7.3, 1.4, and 283.8 times the background values, respectively, which were influenced by anthropogenic sources. The geo-accumulation index (Igeo) indicated that Cd, Zn, Pb, Cu, and As were highly polluted. The potential ecological risk indexes indicated that the potential risk of Cd was extremely high in winter. Source apportionment results were obtained using the enrichment factor (EF) and principal component analysis (PCA), and the results showed that soil dust, vehicle emission, coal burning, and metal smelting were the main sources of metallic elements in ambient PM2.5 during winter in Zibo City.

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