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德州市夏季臭氧敏感性特征及减排方案
摘要点击 2911  全文点击 856  投稿时间:2020-01-23  修订日期:2020-03-25
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中文关键词  臭氧  敏感性分析  高阶直接去耦合法(HDDM)  减排方案  时空特征
英文关键词  ozone  sensitivity analysis  higher-order decoupled direct method (HDDM)  reduction controls  spatial-temporal characteristics
作者单位E-mail
严茹莎 上海市环境科学研究院, 国家环境保护城市大气复合污染成因与防治重点实验室, 上海 200233 yanrs@saes.sh.cn 
中文摘要
      近年来德州市臭氧污染频发,2018年夏季(6~8月),德州市发生了严重臭氧污染事件,臭氧日最大8 h浓度值超标天数达60 d,超标率65%,3个月平均值为176 μg ·m-3,最高达262 μg ·m-3.本研究利用WRF-CAMx耦合的HDDM模块,分析期间德州臭氧敏感性特征及减排方案.结果表明,在空间上,德州市中心城区为VOCs控制区,而郊区为NOx与VOCs协同控制区.在时间上,VOCs敏感值每日为正值,但dO3_V50在6月(城区18.7 μg ·m-3,郊区19.7 μg ·m-3)和8月(城区15.3 μg ·m-3,郊区16.4 μg ·m-3)高于7月(城区13.0 μg ·m-3,郊区11.8 μg ·m-3),NOx敏感值城区呈正负交错,郊区大部分为正值,并与VOCs敏感值接近.对于城区减排方案应考虑以仅VOCs削减为优先,而郊区由于NOx和VOCs对臭氧减排效果相当,建议以NOx:VOCs=1:1为优.
英文摘要
      In recent years, there have been frequent ozone pollution episodes in Dezhou, China. In the summer of 2018 (from June to August), Dezhou experienced serious ozone pollution episodes. The daily 8-hour maximum ozone concentrations exceeded the national standard for 60 days with the standard exceeding ratio of 65%. The average of daily 8-hour maximum ozone concentration was 176 μg ·m-3 over these three months, and the highest value reached was 262 μg ·m-3. In this study, the WRF-CAMx model coupled with the higher-order decoupled direct method (HDDM) was used to analyze the ozone sensitivity and emission control plans in Dezhou during this period. The results showed that ozone formation was in the strong VOC-limited regime in the urban area of Dezhou, while it was in the NOx and VOCs transition regime in suburban areas. VOCs sensitivity values (dO3_V50) were positive every day in summer, which was higher in June (18.7 μg ·m-3 in urban area, 19.7 μg ·m-3 in suburban area) and August (15.3 μg ·m-3 in urban area, 16.4 μg ·m-3 in suburban area) than in July (13.0 μg ·m-3 in urban area, 11.8 μg ·m-3 in suburban area). NOx sensitivity values (dO3_N50) were positive or negative in the urban area, and most days were positive in the suburban area, which were close to the VOCs sensitivity values. For urban areas, VOC reduction should be the priority for emission reduction plans, whereas for suburban areas, NOx:VOCs=1:1 is recommended because the reductions in NOx and VOCs emissions had the same effect on ozone pollution control.

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