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西藏普莫雍错湖芯沉积物中重金属的垂向分布特征及生态风险评估
摘要点击 2492  全文点击 1474  投稿时间:2014-03-29  修订日期:2014-06-09
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中文关键词  普莫雍错  青藏高原  重金属  沉积物  湖泊
英文关键词  Pumoyum Co  Tibetan Plateau  heavy metals  sediment  lake
作者单位E-mail
谢婷 中国科学院生态环境研究中心环境化学与生态毒理学国家重点实验室, 北京 100085 xieting118@126.com 
罗东霞 中国科学院生态环境研究中心环境化学与生态毒理学国家重点实验室, 北京 100085  
杨瑞强 中国科学院生态环境研究中心环境化学与生态毒理学国家重点实验室, 北京 100085 rqyang@rcees.ac.cn 
中文摘要
      2008年7月采集了青藏高原南部普莫雍错的湖芯沉积物样品,利用微波消解和电感耦合等离子体质谱(ICP-MS)、电感耦合等离子体发射光谱仪(ICP-OES)分析了样品中Cr、Co、Ni、Cu、Zn、Cd、Pb、Mn和Fe的含量,其平均浓度分别为26.4 μg·g-1、6.64 μg·g-1、16.2 μg·g-1、26.2 μg·g-1、50.2 μg·g-1、0.363 μg·g-1、16.8 μg·g-1、0.302 mg·g-1和9.84 mg·g-1,略高于南极沉积物,但低于人类影响较大的云南滇池、内蒙古岱海、北美五大湖和太湖相应浓度,处于较低浓度水平. 重金属垂向浓度分布波动较小,表层浓度较高. 主成分分析和聚类分析结果表明,有机质和Mn受地表径流陆源碎屑输入影响较大,而其他重金属主要受天然成岩风化及大气沉降影响. 采用沉积物质量基准法和潜在生态风险指数法进行生态风险评估,结果表明普莫雍错沉积物中重金属的生态风险水平较低.
英文摘要
      The sediment core was collected in Pumoyum Co, a lake located in southern Tibetan Plateau, in July 2008. Samples were digested using microwave equipment and analyzed by Inductively Coupled Plasma Mass Spectrometry (ICP-MS) and Inductively Coupled Plasma Optical Emission Spectrometry (ICP-OES) to determine the content of heavy metals in the sediments. The average concentrations for Cr, Co, Ni, Cu, Zn, Cd, Pb, Mn and Fe were 26.4 μg·g-1, 6.64 μg·g-1, 16.2 μg·g-1, 26.2 μg·g-1, 50.2 μg·g-1, 0.363 μg·g-1, 16.8 μg·g-1, 0.302 mg·g-1 and 9.84 mg·g-1, respectively. The concentrations of analysed metals in Pumoyum Co were slightly higher than those in Antarctic, but lower than those from Dianchi in Yunnan, Daihai in Inner Mongolia, the Great lakes in North America and Taihu in China, which were obviously affected by anthropogenic activities. Overall, these metals in sediments from Pumoyum Co represented a low concentration level. Vertical profiles of heavy metals in the sediment core kept stable without large fluctuation and the concentrations in surface slices were relatively higher. Results of principle component analysis and cluster analysis indicated that organic matter and Mn were affected by surface runoff markedly while other metals were mainly correlated to natural diagenetic weathering and atmospheric deposition. Sediment quality guideline and potential ecological risk index were introduced to assess sediment quality and both of their results indicated that the Pumoyum Co as a whole can be ranked as low potential ecological risk.

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