首页  |  本刊简介  |  编委会  |  投稿须知  |  订阅与联系  |  微信  |  出版道德声明  |  Ei收录本刊数据  |  封面
焚烧飞灰卫生填埋共处置的螯合稳定化技术研究
摘要点击 1718  全文点击 1200  投稿时间:2007-05-10  修订日期:2007-08-16
查看HTML全文 查看全文  查看/发表评论  下载PDF阅读器
中文关键词  焚烧飞灰  稳定化  共处置  螯合反应
英文关键词  MSWI fly ash  stabilization  co-disposal  chelating reaction
作者单位
叶暾 清华大学环境科学与工程系北京 100084
哈尔滨工业大学市政环境工程学院
哈尔滨 150090 
王伟 清华大学环境科学与工程系北京 100084 
高兴保 清华大学环境科学与工程系北京 100084 
万晓 清华大学环境科学与工程系北京 100084 
中文摘要
      对4种垃圾焚烧飞灰的性质进行了分析,其主要元素以Si、Ca、Al、Cl等为主,此外还含有相当数量的重金属如Pb、Zn、Cu、Cr、Cd等,存在很大的环境风险.而飞灰进入卫生填埋场进行共处置是现实可行的出路,为保证共处置的安全性,针对共处置情景制订的浸出毒性浸出方法提高了浸取液酸强度(0.3 mol·L-1,以H+计), 此浸出方法已于2007-05-01日开始执行.采用二硫代氨基甲酸盐(dithiocarbamate)类螯合剂对焚烧飞灰进行了稳定化处理工艺实验,结果表明,DTC类螯合剂通过螯合反应作用于飞灰中的重金属,当DTC类螯合剂投加量为3%(质量分数)时,4种飞灰中重金属的浸出值均能达到在卫生填埋场和垃圾进行共处置的要求.
英文摘要
      The characteristics and leaching behavior of heavy metals in fly ash, sampled from 4 MSWI plants, were investigated in this study. The results indicated that the main elements of fly ash were Si,Ca,Al,Cl,and heavy metals such as lead, zinc, copper, chromium and cadmium were enriched in fly ash which had great environmental risk. However, co-disposal of fly ash in sanitary landfill was an available and practical resolvent. For disposal security, the leaching procedure of toxicity basing on co-disposal scenario, which had been implemented from 1st May 2007, had increased the acidity of leachant to 0.3 mol·L-1. The experiments of chelating stabilization technology using dithiocarbamate were carried out for MSWI fly ash treatment. The results indicated that heavy metals in fly ash were fixed by DTC in manner of chelating reaction. With the amount of additive reaching 3%(mass fraction),the concentrations of heavy metals in leachate of these fly ash samples could meet the demand of co-disposal in sanitary landfill.

您是第52925423位访客
主办单位:中国科学院生态环境研究中心 单位地址:北京市海淀区双清路18号
电话:010-62941102 邮编:100085 E-mail: hjkx@rcees.ac.cn
本系统由北京勤云科技发展有限公司设计  京ICP备05002858号-2