| 铁氧化物与电子供体基质交互作用对红壤性水稻土中DDT还原脱氯影响 |
| 摘要点击 1905 全文点击 1091 投稿时间：2014-04-03 修订日期：2014-05-29 |
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| 中文关键词 DDT 还原脱氯 针铁矿 有机碳 土壤 |
| 英文关键词 DDT reductive dechlorination goethite organic carbon soil |
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| 中文摘要 |
| 铁氧化物与电子供体基质交互作用对电子转移及具有脱氯功能的铁还原菌生长有重要影响，进而可能影响土壤中多氯代有机物的还原脱氯降解. 本研究采用土壤厌氧培养实验，分析铁氧化物（针铁矿）和电子供体基质（正丁酸和乙醇）及其交互作用对红壤性水稻土中DDT脱氯的影响及其机制. 结果表明，由于DDT脱氯降解，DDT及其降解产物与土壤形成结合态残留，厌氧培养6周后，土壤中DDT可提取态残留量仅为初始量的1.29%~2.01%. DDT厌氧脱氯降解的主要产物为DDD. 在培养前期，加入正丁酸和乙醇使反应体系的pH降低Eh增加，进而不利于DDT还原脱氯降解. 添加针铁矿或者同时添加针铁矿和电子供体基质均使反应体系的pH增加Eh降低，并且增加土壤中二价铁的量，从而促进DDT还原脱氯降解. 正丁酸和铁氧化物对DDT还原脱氯无显著交互作用，而乙醇和铁氧化物对DDT还原脱氯具有拮抗作用. 本研究结果对于制定DDT污染土壤的高效原位修复技术方案具有重要意义. |
| 英文摘要 |
| The interaction between iron oxide and electron donor substance have significant influences on electron transfer and the growth of iron-reducing bacteria, which may affect the reductive dechlorination of polychlorinated organic compounds in soil. Anaerobic soil incubation experiment was conducted to study the effect and its mechanism of iron oxide (goethite), electron donor substances (butyrate and ethanol), and their interaction on DDT reductive dechlorination in Hydragric Acrisols. Results showed that after 6 weeks of anaerobic incubation, the extractable residues of DDT were between 1.29% and 2.01% of initial DDT amounts in soils, which was attributed to the dechlorinated degradation of DDT and formation of bound residues of DDT and its dechlorinated products. The main product of DDT anaerobic dechlorination was 1,1-dichloro-2,2-bis (p-chloro-phenyl) ethane (DDD). During the prophase of incubation, the application of butyrate or ethanol led to the decreased pH and increased Eh for reaction system, thus inhibited DDT dechlorination. The applications of only goethite or goethite and electron donor substances resulted in the increased soil pH, decreased soil Eh and increased Fe(Ⅱ) contents, thus accelerated DDT dechlorination. There was no significant interaction between butyrate and iron oxide on DDT dechlorination, whereas there was antagonistic action between ethanol and iron oxide on DDT dechlorination. The results will be of great significance for developing efficient and in-situ remediation technology of DDT contaminated soil. |
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