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扎当冰川雪坑中不同粒径微粒元素和矿物组成特征
摘要点击 1547  全文点击 2929  投稿时间:2010-12-14  修订日期:2011-04-26
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中文关键词  扎当冰川  不溶性微粒  质子激发X荧光(PIXE)  X射线衍射(XRD)  富集因子  后向轨迹
英文关键词  Zadang Glacier  insoluble microparticle  particle-induced X-ray emission (PIXE)  X-ray diffraction (XRD)  enrichment factor  backward trajectory
作者单位
余光明 中国科学院寒区旱区环境与工程研究所冰冻圈科学国家重点实验室 兰州 730000 
徐建中 中国科学院寒区旱区环境与工程研究所冰冻圈科学国家重点实验室 兰州 730000 
康世昌 中国科学院青藏高原研究所 北京 100085 
黄杰 中国科学院青藏高原研究所 北京 100085 
任贾文 中国科学院寒区旱区环境与工程研究所冰冻圈科学国家重点实验室 兰州 730000 
中文摘要
      为了研究雪冰中不溶性微粒的矿物和元素组成及其来源,2009年5月和7月在念青唐古拉山扎当冰川垭口采集了2个雪坑样品,采用质子激发X荧光分析(PIXE)和X射线衍射定量分析方法(XRD)测定了不同季节粗细微粒(d>10 μm和0.22 μm<d<10 μm)的元素和矿物组成.结果表明,微粒矿物组成主要为石英、 云母、 方解石,此3种矿物比重分别占粗细微粒已检测矿物的71.5%和76.5%.微粒元素组成以Si、 Al、 Fe、 K、 Mg、 Ca等地壳元素为主,6种元素分别占粗细微粒所测元素浓度的97%和85.1%,S、 Cl、 P等元素在细微粒中也占相当的比例.粗微粒元素组成的季节变化较小,细微粒元素组成的季节波动则较大.元素富集因子的研究表明,Mg、 Ca、 Si、 K、 Ca、 Ti、 V、 Mn等元素多来自于自然源; 在夏季风期间细微粒中Sc、 P、 Cr、 S、 Cl等元素有明显的富集.气团轨迹显示夏季风期间气团主要来自南亚地区,这些元素可能来自南亚污染物质的输入; 而非季风期间气团主要来自西亚和南亚的干旱及半干旱区.结果表明,扎当冰川雪坑中粗微粒可能主要源于远源或局地矿物粉尘的贡献,细微粒化学组成受到人类污染物的干扰.
英文摘要
      In order to study the mineral and elemental composition of insoluble microparticles (IP) in snow/ice, two snowpits were collected from the Zadang Glacier in Mt. Nyainqentanglha (30.47°N, 90.65°E, 5800 m a.s.l) in May and July, 2009, and IP samples were investigated. The measurements of mineral composition with different size fractions (d>10 μm and 0.22 μm<d<10 μm) were carried out using Particle-induced X-ray emission (PIXE) and X-ray diffraction analysis (XRD). The main mineral components of both coarse and fine IP are quartz, mica and calcite, accounting for 71.5% and 76.5%, respectively. The crustal elements concentrations (e.g. Si, Al, Fe, K, Mg and Ca) are 97% and 85.1% of total coarse/fine IP, while S, Cl and P take fairly proportion in fine microparticles (d<10 μm). Seasonal variability of mineral composition in coarse microparticles (d>10 μm) is not obviously; However it's significantly in fine IP. Enrichment factors (EF) analysis reveals that several elements (e.g. Sc, P, Cr, S and Cl) in fine IP during monsoon season have high values which indicate these elements may be influenced by anthropogenic activities. Backward air mass trajectory analysis suggests that air masses in this region mainly originate from the South Asia areas during monsoon season, and air masses mainly come from arid/semi-arid region in the South and West Asia during non-monsoon season. Therefore, anthropogenic pollutants from the South Asia may be transported by the summer Indian monsoon to the Zadang glacier area. The coarse IP may derive from the local or remote mineral dust, and chemical compositions of fine IP interfere with anthropogenic pollutants.

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