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应用Modified Gompertz模型对城市生活垃圾沼气发酵的拟合研究
摘要点击 1722  全文点击 1469  投稿时间:2010-06-03  修订日期:2010-09-20
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中文关键词  Modified Gompertz模型  城市生活垃圾  沼气发酵  料菌比  发酵含量  挥发性固体
英文关键词  Modified Gompertz model  organic fraction of municipal solid waste  anaerobic digestion  ratio of feedstock to inoculum  fermentative concentration  volatile solid(VS)
作者单位
李建昌 昆明理工大学固体废弃物资源化国家工程中心昆明650031云南师范大学可再生能源材料先进技术与制备教育部重点实验室 昆明650092 
孙可伟 昆明理工大学固体废弃物资源化国家工程中心昆明650031 
何娟 昆明理工大学固体废弃物资源化国家工程中心昆明650031 
吴勇生 昆明理工大学固体废弃物资源化国家工程中心昆明650031 
中文摘要
      尽管Modified Gompertz模型与料菌比和发酵浓度之间没有直接的函数和变量关系,但是料菌比和浓度的变化必然导致Modified Gompertz模型参数的改变,因此可以通过Modified Gompertz模型参数的变化特征对料菌比和发酵浓度是否适宜作出合理的评价.据此本研究将采用中温批量发酵,分别设计单因素实验和多因素均匀设计(Uniform Design)实验,并利用Modified Gompertz模型拟合的方法,同时考察料菌比和发酵浓度对城市生活垃圾批量沼气发酵的影响.结果表明,累积产气量随时间的变化与Modified Gompertz 模型具有较好的相关性,从而获得最大累积产气量、最大产气速率和滞留时间模型参数,并由此推算出VS产气率及产气速率等评价指标.这些参数和指标的变化特征表明,发酵含量是影响最大累积产气量、最大产气速率、VS产气率和VS产气速率的主要因素,而料菌比的影响相对较小,特别是对VS产气率和VS产气速率几乎不产生影响,并表明城市生活垃圾沼气发酵的VS含量在4%~8%比较适宜,料菌比在1.5∶1~2.5∶1比较适宜.
英文摘要
      Although there was not direct correlation between modified Gompertz model (MGM) and ratio of feedstock to inoculum (RFI) and fermentative concentration (FC),the changes of RFI and FC absolutely resulted in the change of MGM's parameters,so it could make a suitable estimation for RFI and FC by means of the characteristic value of MGM's parameters.Based on this theory,MGM was used to investigate the effect of both RFI and FC on batch mesophilic anaerobic digestion of organic fraction of municipal solid waste (OFMSW) by using single-factor experiment and Uniform Design multi-factor experiment.The results showed that accumulative biogas yield as a function of time had an strong excellent correlation with MGM from which kinetic parameters of anaerobic digestion,such as the maximum accumulative biogas yield,the maximum biogas rate,lag-phase time,biogas potential of VS,and biogas rate of VS,could be directly or indirectly obtained.The characteristics of these kinetic parameters indicated that fermentative concentration had a greater influence on the maximum accumulative biogas yield,the maximum biogas rate,biogas potential of VS,and biogas rate of VS,while the ratio of feedstock to inoculum had a less or no impact on those parameters,especially biogas potential of VS and biogas rate of VS.It also indicated that the optimum VS concentration for anaerobic digestion of OFMSW was 4%-8% and ratio of feedstock to inoculum was 1.5∶1-2.5∶1.

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