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兰州市城区河道表层沉积物重金属污染及磁学参数相关关系研究
摘要点击 3125  全文点击 2428  投稿时间:2010-05-22  修订日期:2010-09-16
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中文关键词  沉积物  重金属  环境磁学  生态风险评价  地质累积指数  富集因子  兰州市
英文关键词  river sediment  heavy metal  environmental magnetism  ecological risk  geoaccumulation  enrichment factor  Lanzhou
作者单位
王博 兰州大学西部环境教育部重点实验室兰州730000 
赵爽 兰州大学西部环境教育部重点实验室兰州730000 
夏敦胜 兰州大学西部环境教育部重点实验室兰州730000中国科学院寒区旱区环境科学与工程研究所兰州730000 
余晔 中国科学院寒区旱区环境科学与工程研究所兰州730000 
田世丽 中国科学院寒区旱区环境科学与工程研究所兰州730000 
贾佳 兰州大学西部环境教育部重点实验室兰州730000 
蒋小荣 兰州大学资源环境学院兰州 730000 
中文摘要
      以兰州市城区8条河流的表层沉积物为研究载体,通过Hkanson潜在生态风险指数法、 地质累积指数法及富集因子评价法等3种污染评价指标以及环境磁学方法对As、Co、Cr、Cu、Ni、Pb、V、Zn共8种重金属元素污染特征进行分析.结果显示,①元素As、 Co、 Ni、 V在8条河流中均表现为轻微生态危害;元素Cr、 Pb、 Zn在鱼儿沟下游表现为中等生态危害;元素Cu在鱼儿沟中下游表现为很强生态危害;②各条河流重金属污染程度表现为:污染较轻的河流有大沙沟和罗锅沟,属轻微污染型;排洪沟、 水磨沟、 寺儿沟及鱼儿沟污染相对严重的区域均位于下游地区,表现为末端污染富集型;七里河上游污染相对最为严重,表现为源头污染富集型;烂泥沟上游和下游均有较为严重的污染;③通过兰州市河道表层沉积物重金属元素以及3种评价指标与磁学参数相关关系研究发现,Cr、 Ni、 Pb、 Zn、 Cu与表示磁性矿物总体含量的参数(χ 、 SIRM、 Ms)之间均具有良好的相关性,Pb与χARM之间良好的相关性则显示了Pb与单畴亚铁磁性颗粒密切相关,粗晶粒磁性矿物与Cr、 Ni、 Pb、 Zn良好的负相关,进一步说明磁晶粒度越大,元素含量越高,人为影响越严重;④表示磁性矿物含量的参数(χ、 SIRM、 SOFT 、 Ms)与地质累积指数(Igeo)相关性显著高于潜在生态风险指数(RI)和总富集因子(R),反映出磁学参数对低污染指示较为敏感,同时也表明应用磁测方法研究城市河流沉积物污染分布,评价重金属元素污染程度的可行性与可靠性.
英文摘要
      The contents of As,Co,Cr,Cu,Ni,Pb,V and Zn in the surface sediments from 8 rivers in urban area in Lanzhou were monitored by ecological risk which was assessed by the potential ecological Hkanson index,and the index of geoaccumulation(Igeo),sediment enrichment factor(R),and environmental magnetism. The results showed that: ①the potential ecological risk of heavy metals of As,Co,Ni,V in surface sediments from 8 rivers were low,which belonged to low ecological risk. But the risk of heave metals Cr,Pb,Zn in surface sediments from Yuer river was high,which belonged to middle ecological risk,and in downstream of Yuer river,the element of Cu belonged to high ecological risk. ②The rivers in Lanzhou could be divided into four groups according to the heavy mental pollution degree: first type,such as Paihong river,Shier river,Yuer river and Shuimo river,called downstream concentrate type;second type,such as Qili river,called upstream concentrate type;third type,such as Luoguo river and Dasha river,called less affected type;fourth type,Lanni river,which polluted heavily in up and downstream;③The correlation analysis between magnetic parameters and element contents show that the parameters which mainly reflect the concentration of the magnetic minerals(χ,SIRM,Ms)have close association with Cr,Ni,Pb,Zn,Cu,So we can infer that the magnetic minerals in deposits samples mainly came from electroplating effluent,motor vehicle emission,and domestic sewage. SIRM/χ shows a strong correlation with Cr,Ni,Pb,Zn,indicating the distribution of anthropogenic particulates. ④The magnetic minerals(χ, SIRM, Ms) have a strong correlation with the geoaccumulation(Igeo) than potential ecological risk index and enrichment factor(R).These results suggest a possible approach for source identification of magnetic material in pollution studies and the validity of using magnetic measurements to mapping the polluted area.

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