Distribution of Thallium(Tl),Cadmium(Cd),Chromium(Cr),Lead(Pb),Nickel(Ni),Arsenic(As),Copper(Cu),Zinc(Zn) in water and sediments of Yunfu pyrite mine area was studied. The environmental risk assessment was conducted systematically using Sediment Quality Guidelines (SQGs) and Hakanson potential ecological risk index. The results indicated that concentration range of Tl in stream water was 0.19-65.25 μg/L,which is higher than the environmental quality standards for surface water. Concentration ranges of Tl,Zn,As,Cd,Pb in sediments were 5.89-63.0 mg/kg,1 215-5 754 mg/kg,208.4-1 327 mg/kg,4.20-17.5 mg/kg,282-13 770 mg/kg. According to Sediments Quality Guidelines,sediments was moderately to severe level of pollution since concentrations of Tl,Cd,Cr,Pb,Ni,As,Cu,Zn were much higher than LEL (lowest effect level) values,and the concentrations of Pb,As,Zn were higher than SEL (severe effect level) values,the others were partly higher than SEL values,which may result in severe negative biota effects in the watersheds. Compared to soil background values of Guangdong province,the metals in stream sediment showed strong to severe strong ecological risk,and the ecological risk of heavy metals in the descending order of Tl,Cd,As,Pb,Cr,Ni,Zn and Cu. Besides,the sediments were severe contained by toxic element thallium and cadmium. Besides,the mainly ecological risk of heavy metal is thallium. More emphasis should be placed on thallium and cadmium control and disposal in future. |