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开放式空气CO2增高条件下稻田磷化氢气体的释放研究
摘要点击 2283  全文点击 1712  投稿时间:2008-10-29  修订日期:2009-03-10
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中文关键词  FACE  磷化氢  释放通量  浓度  水稻田
英文关键词  free air carbon dioxide enrichment(FACE)  phosphine  emission fluxes  concentration  paddy field
作者单位
张蕤 南京师范大学化学与环境科学学院南京210097 
杨小弟 南京师范大学化学与环境科学学院南京210097 
耿金菊 南京大学环境学院污染控制与资源化研究国家重点实验室南京 210093 
洪宇宁 南京大学环境学院污染控制与资源化研究国家重点实验室南京 210093 
顾雪元 南京大学环境学院污染控制与资源化研究国家重点实验室南京 210093 
王晓蓉 南京大学环境学院污染控制与资源化研究国家重点实验室南京 210093 
王睿 中国科学院大气物理研究所北京100029 
朱建国 中国科学院南京土壤研究所南京210008 
中文摘要
      磷化氢(PH3)已被证实是大气中普遍存在的痕量气体. 采用FACE(free air carbon dioxide enrichment)平台,研究了不同氮施肥水平(常氮250 kg/hm2和低氮125 kg/hm2)下,CO2浓度升高对水稻田磷化氢释放通量的影响. 结果表明,水稻生长旺盛期(分蘖,拔节)磷化氢通量和浓度高于生长缓慢期,FACE圈常氮区分蘖期磷化氢释放通量最大,为(155.2±22.71) ng/(m2·h). 整个水稻生长期磷化氢平均释放通量最大值在FACE圈常氮区观察到,为(41.72±7.06) ng/(m2·h),最小值(-1.485±6.229) ng/(m2·h)出现在对照圈低氮区. FACE处理显著促进磷化氢的排放,不同氮素水平对磷化氢释放影响差异不显著. 磷化氢的净通量和浓度与温度均呈显著正相关. 对水稻成熟期全天释放通量及浓度测试表明,光照是影响白天磷化氢浓度的主要因素.
英文摘要
      Phosphine, a trace gas, has been proved to commonly exist in environment. Under free air carbon dioxide enrichment (FACE) condition, the phosphine fluxes were investigated on the function of different nitrogen fertilizer application, NN (normal N, 250 kg/hm2) and LN (low N, 125 kg/hm2). Results showed that phosphine fluxes and concentrations in flourishing stages, both tillering stage and elongation stage, were higher than in slowly growing stages. The highest phosphine flux of (155.2±22.71) ng/(m2·h) was observed in tillering stage in NN zone of the FACE area. The highest average phosphine flux of (41.72±7.006) ng/(m2·h) was observed in NN zone of FACE area, while the lowest average phosphine flux of (-1.485±6.229) ng/(m2·h) could be detected in LN zone of the ambient area. CO2 enrichment can obviously improve the phospine emission. The nitrogen fertilizing level doesn’t play an important role in phosphine emission. Both net fluxes and concentrations of phosphine had obviously positive correlation with temperature. A one-day phosphine flux and concentration experiment was carried out in ripening stage. The result showed that light was the prominent factor influencing phosphine concentration in daytime.

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