| Hg, Pb, Cd, Zn, and Cu concentrations in the soil, vegetables and crop of Huludao city were investigated. The Hg, Pb, Cd, Zn, and Cu concentrations in soils of the smelting areas are 1.422, 443.1, 60.94, 4 084, and 247.8 mg·kg-1, thus 6.092, 3 195, 341.7, 35 157, and 1 557 mg·kg-1 for the maximal concentrations, respectively. Spatial distribution maps of heavy metals concentrations in top soils in Huludao City were separately laid out by using Kriging. Heavy metals spatial distribution patterns in soils show that Pb, Cd, Zn, Cu emissions from Huludao Zinc Plant are the main pollution sources of heavy metals to the top soils in Huludao City, but Hg emission from Huludao Zinc Plant and chlor-alkali industry is the main pollution source of mercury to the top soils. Heavy metals concentrations in top soils decrease exponentially with distance from the zinc smelting area. Except Hg, the exponential equation could be better to fit the variety for other heavy metals. Heavy metals in vegetable and crop cultivated around Huludao Zinc Plant are higher than from markets, suggests that heavy metals affect the local soil and crops seriously. |
