| The concentration of HONO, NO2, O3 and other atmospheric pollutants were observed continuously by using differential optical absorption spectroscopy (DOAS) from 2007-08-14 to 2007-08-24 in Beijing, China. Diurnal variation characteristics of HONO and NO2 were analyzed. The HONO levels originated from the nocturnal direct emission were discussed. And the correlation between the heterogeneous formation of HONO and its related factors (BC, RH, and so on) was studied. The results showed that HONO had two peaks at about 01:00 and 06:00, respectively, while two peaks of NO2 concentrations appeared at about 01:00 and 07:00. The highest HONOem/HONO ratio of 31.3% was observed at about 20:00 between 19:00 to 07:00, and the average ratio was 15%. Good correlation of HONOcorr/NO2 ratio with BC and RH at night was obtained. The correlation suggested that heterogeneous NO2 to HONO conversion processes may occur on BC surfaces by reaction with absorption water, and the average nighttime conversion frequency from NO2 into HONO (HONO/NO2) was calculated about 0.8%·h-1. At the same time, the results showed that heterogeneous formation of HONO was increased with RH and inhibited at RH>80%, and the hypothesis was further supported by detailed analysis of selected case. |
