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我国北方城市污水处理厂二级处理出水的水质特性
摘要点击 2124  全文点击 1708  投稿时间:2008-05-21  修订日期:2008-08-11
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中文关键词  二级出水  水质分析  有机物分离  污水回用
英文关键词  secondary effluent  analysis of water characteristic  organic matter fractionation  water reuse
作者单位
王树涛 哈尔滨工业大学市政环境工程学院哈尔滨150090 
王虹 哈尔滨排水有限责任公司, 哈尔滨150010 
马军 哈尔滨工业大学市政环境工程学院哈尔滨150090 
章广德 哈尔滨市环境工程评估中心, 哈尔滨150076 
刘惠玲 哈尔滨工业大学市政环境工程学院哈尔滨150090 
中文摘要
      将生活污水二级处理出水分离为悬浮态、近胶体态和溶解态物质,并分别进行了分析.结果表明,溶解态COD占二级出水总COD的78.2%~86.5%,而悬浮态COD仅占10.1%~17.0%,近胶体态COD最高占4.8%;溶解态TOC占二级出水总TOC的82.6%~86.6%;悬浮物中有机组分占物质总量的75.54%~89.93%;二级出水中80%的颗粒分布在2.00~6.84 μm之间;二级出水的可生化性较差:BOD5/COD为0.195~0.283, BDOC/DOC为0.156~0.26.溶解性有机物和悬浮性有机物的GC/MS分析表明,具有环状结构的化合物分别占各自总化合物的58%和35%.分析认为,二级出水中大多为难降解有机物,可生化性很差,要实现较高的去除效率,必须首先改善其可生化性,才能充分发挥后续生化工艺净化有机物的潜力.
英文摘要
      The secondary effluent from a municipal sewage treatment plant was fractionated into three parts: the dissolved, the near-colloidal and the suspended. The variation of each composition was investigated individually during winter, spring and summer. The fractionation study revealed that the dissolved COD and DOC accounted for 78.2%-86.5% of total COD and 82.6%-86.6% of TOC, respectively. The molecular weight distribution (MWD) of the secondary effluent indicated that the organics with molecular weight (MW) <1 000 accounted for 56.3%-62.8% of total organics. The organic components constituted 75.54%-89.93% of the mixture of suspended and near-colloidal matter. The size distribution of the particles showed that the particles ranging from 2.00 to 6.84 μm constituted more than 80% of the total particles. The secondary effluent was relatively poor biodegradable with only 0.195-0.283 of BOD5/COD ratio and 0.156-0.26 of BDOC/DOC ratio. The GC/MS analysis detected 43 and 26 kinds of compounds in dissolved and in suspended forms, respectively, and most of them are bio-refractory according to the functional groups of the chemicals. Biodegradability of the secondary effluent should be enhanced for improving the sequential biochemical removal efficiency for the organic matter.

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