利用玉米浸泡液产电的微生物燃料电池研究 |
摘要点击 2969 全文点击 1563 投稿时间:2008-04-02 修订日期:2008-05-20 |
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中文关键词 微生物燃料电池 玉米浸泡液 “三合一”膜电极 产电 |
英文关键词 microbial fuel cell(MFC) corn steepwater assembly membrane electrode power generation |
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中文摘要 |
以玉米淀粉生产过程中的浸泡液(玉米浸泡液)作为接种液和基质,利用“三合一”膜电极的单室空气阴极微生物燃料电池进行试验,采用在线监测电压和废水分析方法对产电功率和化学需氧量(COD)、氨氮进行测定,探讨高COD、高氨氮有机废水产电及废水处理的可行性.结果表明,经过94 d(1个周期)的连续运行(固定外电阻为1 000 Ω),17 d时输出电压达到最大(525.0 mV),稳定期最大输出功率可达169.6 mW/m2,此时电池相应的电流密度为440.2 mA/m2,内阻约为350 Ω,开路电压619.5 mV;但燃料电池电子利用效率较低(库仑效率为1.6%);1个周期结束时浸泡液的COD去除率达到51.6%,氨氮去除率25.8%.本试验利用玉米浸泡液成功获得电能,同时对浸泡液有效地进行了处理,为其资源化利用提供新途径. |
英文摘要 |
Corn steepwater containing 49 732.2 mg/L of chemical oxygen demand (COD) was used as fuel for a membrane electrode assembly microbial fuel cell (MEA-MFC),which could generate electricity and treat the wastewater at the same time.During a batch experiment of 94 days with a fixed 1 000 Ω external resistance,the maximum voltage output of 525.0 mV and power density of 169.6 mW/m2 were obtained after 17 days,corresponding to the current density,internal resistance and open voltage of 440.2 mA/m2, 350 Ω and 619.5 mV,respectively.However,data showed that the coulombic efficiency was only 1.6%,suggesting very limited COD was utilized for electricity generation.At the conclusion of the test,the removals of COD and ammonia-nitrogen were achieved 51.6% and 25.8%,respectively.This study demonstrates that corn steepwater can be used for power generation in MFC with simultaneous accomplishments of wastewater treatment,providing a novel approach for the safe disposal and recycle of corn steepwater. |