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填料型微生物燃料电池产电特性的研究
摘要点击 1966  全文点击 1146  投稿时间:2007-03-31  修订日期:2007-06-12
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中文关键词  微生物燃料电池  填料  内阻
英文关键词  microbial fuel cell  packing materials  internal resistance
作者单位
梁鹏 清华大学环境科学与工程系环境模拟与污染控制国家重点实验室北京 100084 
范明志 清华大学环境科学与工程系环境模拟与污染控制国家重点实验室北京 100084 
曹效鑫 清华大学环境科学与工程系环境模拟与污染控制国家重点实验室北京 100084 
黄霞 清华大学环境科学与工程系环境模拟与污染控制国家重点实验室北京 100084 
黄正宏 清华大学新型炭材料研究室北京 100084 
王诚 清华大学核能与新能源技术研究院北京 100084 
中文摘要
      将石墨和碳毡作为阳极填料组装成填料型微生物燃料电池,其启动期在1 d左右,低于平板型微生物燃料电池的启动期.碳毡作为填料时,微生物燃料电池的最大产电功率密度为1 502 mW/m2(37.6 W/m3),优于石墨作为填料的MFC.将碳毡与碳纸烧结一体以提高填料型微生物燃料电池阳极的导电性,与平板型微生物燃料电池相比,其面积内阻从0.071 Ω·m2下降到0.051 Ω·m2,最大电流密度从3 000 mA上升到8 000 mA,最大产电功率密度从1 100 mW/m2(27.5 W/m3)上升到2 426 mW/m2(60.7 W/m3),阳极电势平均下降100 mV.循环流量影响填料型微生物燃料电池的产电能力,当流量低于1 mL/min时,其产电功率密度随流速降低而下降.填料型微生物燃料电池在外电阻为600 Ω下长期稳定运行30 d以上,其库仑效率约为10.6%.
英文摘要
      The packing-type microbial fuel cells (MFCs) were constructed using the granular graphite and the carbon felt as packing materials. The start-up time of the packing-type MFC was about 1 d, which was lower than that of the flat-type MFC. The maximal power density (pm) of the MFC with carbon felt as packing material was 1 502 mW/m2 (37.6 W/m3), which was higher than that with granular graphite as packing material. The carbon felt and carbon paper were sintered together to enhance the electric conductivity. Compared with the flat-type MFC, the area-specific resistance of the packing-type MFC decreased from 0.071 Ω·m2 to 0.051 Ω·m2, the maximal current density increased from 3 000 mA to 8 000 mA, the pm increased from 1 100 mW/m2 (27.5 W/m3) to 2 426 mW/m2 (60.7 W/m3) and the potentials of anode decreased about 100 mV. The flow rate affected the power generation of the MFC. When the flow rate was lower than 1 mL/min, the pm dropped with the flux decreasing. The packing-type MFC was operated for over 30 and the coulomb efficiency was about 10.6%.

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