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中药废水主要成分厌氧生物降解途径研究
摘要点击 2119  全文点击 1556  投稿时间:2006-11-20  修订日期:2007-02-12
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中文关键词  中药废水  厌氧生物降解  降解途径  黄芩甙
英文关键词  traditional Chinese medicine wastewater  anaerobic biodegradation  biodegradation pathway  bacalin
作者单位
施悦 哈尔滨工程大学动力与能源工程学院哈尔滨150001 
任南琪 哈尔滨工业大学市政环境工程学院哈尔滨150090 
章育铭 哈尔滨工业大学市政环境工程学院哈尔滨150090 
肖荣新 大庆市环境监测中心站大庆163316 
中文摘要
      通过小试研究,利用气-质联机(GC-MS)对黄芩甙的厌氧生物降解曲线和途径进行了探讨,对黄芩甙的降解数据进行趋势化模拟和线性回归分析,得到了相应的降解动力学方程.黄芩甙可能的降解途径为“脱糖→脱苯→开环→饱和化→拆链”,降解时间需47 h以上, 厌氧分解的主要产物是小分子氧化物,如醇、醛、酸、酯、烯烃以及还原态饱和烷烃.结果表明,黄芩甙降解的限速步骤在水解酸化阶段,适宜采用两相厌氧消化技术和较长的停留时间进行处理.
英文摘要
      A laboratory-scale experiment was done. And the baicalin anaerobic biodegradation curve and pathway were discussed by analyzing the results of GC-MS. After analogue of status's trend and analysis of its regression, the biodegradation kinetic equation of baicalin was obtained. And the possible biodegradation pathway was “desugar →debentures →open benzene ring →saturating →disconnect links”. It took at least 47 h to biodegrade baicalin. The main products of anaerobic biodegradation were micro-molecule oxide, such as alcohols, aldehydes, acids, esters, olefin, and hydrocarbon of methane series. This result demonstrated that the rate-limiting steps of bacalin biodegradation were the hydrolyzing and acidification phase. It was suitable to use two-phase anaerobic process and long HRT to biodegrade baicalin.

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