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生物柴油排放微粒特性的试验研究
摘要点击 1196  全文点击 892  投稿时间:2006-09-19  修订日期:2006-11-28
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中文关键词  生物柴油  微粒  粒径分布  可溶性有机物  多环芳烃
英文关键词  biodiesel  particle  size distribution  SOF  PAHs
作者单位
葛蕴珊 北京理工大学汽车动力性与排放测试国家专业实验室北京100081 
何超 北京理工大学汽车动力性与排放测试国家专业实验室北京100081 
韩秀坤 北京理工大学汽车动力性与排放测试国家专业实验室北京100081 
吴思进 北京理工大学汽车动力性与排放测试国家专业实验室北京100081 
陆小明 北京理工大学汽车动力性与排放测试国家专业实验室北京100081 
中文摘要
      在1台直喷式增压柴油机上进行了生物柴油和柴油的排放微粒特性试验.用80 L/min定量泵和装有直径90 mm的玻纤滤膜采样器在排气管内采集微粒,利用激光粒度仪和色谱-质谱联用仪,分析了微粒的粒径分布和微粒中的可溶性有机物以及16种多环芳烃.结果表明,生物柴油排放微粒的体积粒径呈单峰分布,其平均直径d32.和中位直径d(0.5)都随转速的增加而减少.高转速时生物柴油排放微粒的d32d(0.5)均高于柴油,而低转速时均低于柴油.生物柴油的SOF排放质量浓度为12.3~31.5 mg/m3,占微粒质量的38.2%~58.0%,均明显高于柴油.生物柴油排放微粒中的总多环芳烃排放浓度为2.9~4.7 μg/m3,与柴油相比下降29.1%~92.4%.
英文摘要
      A particle emission experiment of a direct-injection turbocharged diesel engine with biodiesel and diesel was carried out. A pump of 80 L/min and fiber glass filters with diameter of 90 mm was used to sample engine particles in exhaust pipe. The size distribution, soluble organic fraction (SOF) and 16 polycyclic aromatic hydrocarbons (PAHs) of particles were analyzed by a laser diffraction particle size analyzer and GC-MS. The results indicate that the volume weighted size distribution of biodiesel particle is single-peak and its median diameter d(0.5) and mean diameter d32 are decreased with the increasing speed. At the high speed the d32 and d(0.5) of biodiesel are larger than those of diesel, and quite the contrary at the low speed. SOF mass concentration and mass percentage of biodiesel are 12.3~31.5 mg/m3 and 38.2%~58.0% respectively, which are much higher than those of diesel. The total PAHs emission concentration of biodiesel is 2.9~4.7 μg/m3, lower than that of diesel as much as 29.1%~92.4%.

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