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直链烷基苯磺酸钠在厌氧-缺氧-好氧污水处理系统中的迁移转化规律
摘要点击 1266  全文点击 1255  投稿时间:2006-08-15  修订日期:2006-09-16
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中文关键词  直链烷基苯磺酸钠  AAO系统  迁移转化
英文关键词  linear alkylbenzene sulphonate (LAS)  anaerobic-anoxic-oxic system  transformation
作者单位
黄满红 同济大学环境科学与工程学院国家污染控制与资源化重点实验室上海200092 
李咏梅 同济大学环境科学与工程学院国家污染控制与资源化重点实验室上海200092 
顾国维 同济大学环境科学与工程学院国家污染控制与资源化重点实验室上海200092 
中文摘要
      研究了城市污水处理系统对直链烷基苯磺酸钠(LAS)的去除特性.在厌氧-缺氧-好氧条件下,进行了相应的序批式试验,确定了水相和泥相中LAS降解的动力学参数,建立了LAS在厌氧-缺氧-好氧状态下的去除动力学模型(考虑吸附作用),并对模型预测的结果与实际测量值进行了比较.结果表明,在不同的泥龄下,LAS 在AAO系统中去除率达到99%,出水中只含微量的LAS(0~20 μg·L-1).厌氧池、缺氧池及好氧池LAS污泥吸附量分别为490~710、280~390、69~109 μg·g-1.序批式动力学降解试验还表明,厌氧去除速率系数K、缺氧的去除速率系数K与好氧的去除速率常数的比值分别为0.67和0.71,说明在同一污泥系统的厌氧和缺氧条件下,LAS也能被较好的降解.模型得到的各池混合液出水中LAS的浓度模拟结果与实测结果符合较好(误差<8%).
英文摘要
      The removal characteristics of linear alkylbenzene sulphonate (LAS) was studied in anaerobic/anoxic/oxic (AAO) municipal wastewater treatment processes. A removal (biological degradation and sorption) model was formulated, and kinetic parameters were evaluated with batch experiments under anaerobic, anoxic, oxic conditions. The resulting model calculations were then compared with sampling campaigns performed on AAO process. The results show that the removal efficiency of LAS in the AAO activated sludge processes is more than 99%. Effluent concentrations vary between 0 and 20 μg·L-1. The concentration of LAS adsorbed by sludge in anaerobic tank, anoxic tank, aerobic tank is 490~710 μg·g-1, 280~390 μg·g-1 and 69~109 μg·g-1 respectively. From the result of biodegradation kinetic tests, it can be concluded that LAS is well biodegraded under anaerobic/anoxic/oxic conditions, and the removal rate of LAS in anaerobic and anoxic conditions accounts for respectively 67% and 71% of that in oxic condition. The model can well forecast the effluent quality of anaerobic/anoxic/oxic tank of the AAO process, and the relative error is less than 8%.

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