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黄河中下游表层沉积物中有机氯农药含量及分布
摘要点击 2436  全文点击 1219  投稿时间:2006-08-07  修订日期:2006-09-18
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中文关键词  有机氯农药  沉积物  黄河
英文关键词  organochlorine pesticides  sediments  Yellow River
作者单位
孙剑辉 中国科学院广州地球化学研究所有机地球化学国家重点实验室, 广州510640 
王国良 河南师范大学化学与环境科学学院河南省环境污染控制重点实验室, 新乡453007 
张干 中国科学院广州地球化学研究所有机地球化学国家重点实验室, 广州510640 
李军 中国科学院广州地球化学研究所有机地球化学国家重点实验室, 广州510640 
柴艳 河南师范大学化学与环境科学学院河南省环境污染控制重点实验室, 新乡453007 
王景芝 河南师范大学化学与环境科学学院河南省环境污染控制重点实验室, 新乡453007 
段延佩 河南师范大学化学与环境科学学院河南省环境污染控制重点实验室, 新乡453007 
中文摘要
      利用GC-ECD检测了黄河中下游干支流23个表层沉积物中的有机氯农药,主要检测出HCHs、DDTs、六氯苯、氯丹等,总含量范围为0.35~22.92 ng/g,其中HCHs和DDTs的含量较高,分别为0.09~12.88 ng/g和0.05~5.03 ng/g.干流中有机氯农药的含量从中游到中下游呈逐渐升高趋势,主要支流中的含量为:新蟒河>金堤河>汜水>伊洛河>沁河.干流中HCHs含量较海河、珠江、长江和黄浦江明显偏高;DDTs含量与除海河外的其它河流基本相同,但两者均低于国外河流.沿河流区域工业废水和主要支流的汇入、农药的广泛施用所引起的长期残留与风化土壤是黄河有机氯农药污染的主要来源.
英文摘要
      Organochlorine pesticides (OCPs) in twenty-three sediment samples from the middle and lower reaches of the Yellow River were analyzed by GC-ECD. The OCPs detected were comprised mainly of HCHs, DDTs, hexachlorobenzene, chlordane, etc. The range of total OCPs concentration was 0.35~22.92 ng/g. The concentrations of HCHs and DDTs were much higher than other compounds and varied from 0.05~5.03 ng/g and 0.09~12.88 ng/g, respectively. Contamination level of OCPs in sediment increased from middle to lower reaches along the Yellow River. The distribution of total OCPs in main tributaries followed the sequence: Xinmang River > Jindi River >Si River> Yiluo River >Qin River. The Yellow River had a much higher concentration of HCHs than Hai River, the Pearl River, the Yangtze River and Huangpu River, and almost the same concentration of DDTs as other rivers except Hai River. The contamination of OCPs in the sediments from the middle and lower reaches of the Yellow River derived mainly from industrial contamination in riverbasim, the inflow of the main tributaries and the residues of organochlorine pesticides widely used for a long term and the aged and weathered agricultural soils.

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