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氯化镧改性黏土固化湖泊底泥中磷的研究
摘要点击 2579  全文点击 1060  投稿时间:2006-03-27  修订日期:2006-08-08
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中文关键词  湖泊内源污染治理  氯化镧改性黏土  富营养化  磷去除
英文关键词  treatment of internal phosphorus  clay modified by LaCl3  eutrophication  P removal
作者单位
袁宪正 中国科学院生态环境研究中心环境水质学国家重点实验室北京100085 
潘纲 中国科学院生态环境研究中心环境水质学国家重点实验室北京100085 
田秉晖 中国科学院生态环境研究中心环境水质学国家重点实验室北京100085 
陈灏 中国科学院生态环境研究中心环境水质学国家重点实验室北京100085 
中文摘要
      用氯化镧对14种黏土进行改性并研究了这些改性黏土固化磷的效果.研究了pH对改性高岭土磷吸附率和镧离子溶出的影响.结果表明,通过氯化镧改性,不同黏土的磷固定率由改性前的3%~14%提高到改性后的52%~95%.氯化镧改性高岭土在pH为5时,达到磷吸附率的最大值94.85%,并在pH值4~8范围内,保持较高的磷吸附率(>80%).在pH>6.5的范围,La3+溶出浓度低于0.0178 mg/L.
英文摘要
      14 kinds of clay modified by LaCl3 were prepared and their phosphorus(P) fixation was studied. The effect of pH on adsorption rate of P using kaolin modified by LaCl3 and dissolved concentration of La3+ from them were also discussed. The results showed that the fixation rates of P using clay modified by LaCl3 were improved to 52%~95% from 3%~14% using unmodified clay. The maximum adsorption rate of P using kaolin modified by LaCl3 was 94.85% on the pH value of 5. Under the condition of pH range from 4 to 8, the P adsorption rate was higher than 80%. When the pH value was higher than 6.5, the dissolved concentration of La3+ from the modified clay was lower than 0.017?8mg/L.

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