| 水溶性有机物对土壤吸附-解吸菲的影响 |
| 摘要点击 2544 全文点击 1315 投稿时间：2006-01-20 修订日期：2006-03-09 |
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| 中文关键词 菲 水溶性有机物 吸附 解吸 土壤 |
| 英文关键词 Phe DOM sorption desorption soil |
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| 中文摘要 |
| 以Tween-80为对照,有机物料猪粪(pig manure, PM)、绿肥(green manure, GM)和污泥(sewage sludge, SS)为水溶性有机物(dissolved organic matter, DOM)的提取原料,菲(Phe)为多环芳烃(PAHs)的代表,采用序批试验研究了不同来源DOM对土壤吸附与解吸Phe的影响.结果表明,供试DOM均能明显降低Phe在土壤上的吸附.在DOM试验浓度范围内（0～300 mg·L-1）,土壤对Phe的吸附量与DOM浓度之间呈极显著负直线相关关系(rPM>=-0.988?8,rSS>=-0.982?6,rTween-80>=-0.974?3,rGM>=-0.990?5).菲的吸附等温线可用Freundlich方程定量描述.供试3种DOM抑制土壤吸附Phe和促进土壤吸附Phe的解吸的强弱顺序为:猪粪DOM>污泥DOM>绿肥DOM.本研究结果表明,农业土壤中水溶性有机物能明显活化土壤中的PAHs,增强其在土壤中的移动性. |
| 英文摘要 |
| Batch experiments were conducted to investigate effect of dissolved organic matter (DOM) on the adsorption and desorption behavior of Phenanthrene （Phe） in a soil-water system. It was found that three natural DOM derived from pig manure (PM), sewage sludge (SS), green manure (GM) and a kind of surfactant Tween-80 can reduced sorption of Phenanthrene significantly onto the tested soil.Within the selected concentration of the Phenanthrene and DOM in this study, the sorption quantity has a negative-linear correlativity with the concentration of DOM (rPM>=-0.988?8, rSS>=-0.982?6,rTween-80>=-0.974?3,rGM>=-0.990?5). The inhibition of Phenanthrene sorption caused by DOM of PM origin was more significant than that of SS origin and GM origin for the same soil. Phenanthrene sorption isotherm could be described well by the Freundlich equation. It implied that DOM can affect the environmental behaviors of Phenanthrene in soil. |
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