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固定化酶酸化/UASB两相厌氧有机酸代谢特征
摘要点击 1428  全文点击 1190  投稿时间:2004-12-31  修订日期:2005-02-23
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中文关键词  固定化酶酸化相  两相厌氧  有机酸  乙醇
英文关键词  immobilization enzyme acidfication  two-phase anaerobic fermentation  organic acids  ethanol
作者单位
于宏兵 南开大学环境科学与工程学院 天津300071 
吴睿 吉林大学环境与资源学院 长春130026 
段宁 中国环境科学研究院 北京100012 
林学钰 吉林大学环境与资源学院 长春130026 
黄涛 吉林大学环境与资源学院 长春130026 
中文摘要
      以固定化酶酸化相和UASB产甲烷相为两相厌氧系统进行连续流实验,研究了酸化相和产甲烷相中的有机酸和乙醇的变化特征、变化速率,挥发性有机酸组成,发酵类型以及对COD去除率的影响.结果表明:酸化相的酸化率为28.2%,水解产物组成中乙醇>乙酸>丁酸>丙酸,其中乙醇占44.8%,乙酸占38.4%,丙酸为6.9%,丁酸为9.8%,为乙醇型发酵类型.在产甲烷相中乙醇被去除99.8%,乙酸为92.0%,丙酸为59.1%,丁酸为46.2%,呈乙醇>乙酸>丙酸>丁酸;比较有机酸和乙醇的去除速率呈乙醇>乙酸>丁酸>丙酸,其中乙醇在产甲烷相中去除速率最快为0.21h-1.系统运行稳定,COD去除率达到90%以上,其中对COD去除贡献率顺序为乙醇>乙酸>丁酸>丙酸,
英文摘要
      Using immobilization enzyme acidification phase and UASB to produce methane phase as two-phase anaerobic fermentation process,the change characteristics and the change rate of organic acid and ethanol organic,composition and fermentation type as well as COD removal were studied.The experimental results showed that acidfication rate(VFA/COD) was consistently over 28.2%.The concentration of ethanol,acetic acid,butyric acid and propionic acid in acidfication-phase were 44.8%,38.4%,9.8% and 6.9%,respectively,as follow:ethanol>acetic acid>butyric acid>propionic acid.The removal of ethanol,acetic acid,butyric acid and propionic acid in methane production phase were 99.8%,92.0%,59.1% and 46.2%,respectively,and the removal of COD was higher than 90%.The conversion velocity of substrate in the methane production phase showed as follow:ethanol>acetic acid>butyric acid>propionic acid.The fermentation type of the acidification phase was ethanol-type fermentation.The effect of each acid and ethanol conversion on COD removal was as follow: ethanol>acetic acid>butyric acid>propionic acid.

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