| 类脂/醋酸纤维素复合吸附材料的制备与性能 |
| 摘要点击 1182 全文点击 1430 投稿时间：2004-10-10 修订日期：2005-01-24 |
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| 中文关键词 类脂 醋酸纤维素(CA) 超声辐射 包埋 亲脂性有机污染物 |
| 英文关键词 triolein cellulose acetate (CA) ultrasound irradiation embed lipophilic organic pollutants |
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| 中文摘要 |
| 采用相转化法将类脂包埋到醋酸纤维素(CA)中,制备出了具有对水中低剂量亲脂性有机污染物高效吸附去除的平板膜.以扫描电子显微镜观察了复合材料的结构形貌和表面特征.利用机械搅拌方式和超声方式对类脂进行分散的实验表明,超声对类脂的均匀分散具有强化作用.同时考察了铸膜温度(室温、0℃)对类脂分散的效果,表明低温有助于形成小的脂滴.另外,通过复合膜的红外谱图证实,类脂和CA属于物理混合,不会改变类脂的分子结构,从而不会影响类脂对亲脂性有机污染物的吸附性能.通过荧光分析法分析复合膜在正己烷溶剂中的稳定情况,表明类脂已被完好地包埋到膜中,因而在去除有机污染物的过程中不会从复合膜中渗出. |
| 英文摘要 |
| Triolein is successfully embedded into cellulose acetate (CA) by phase inversion. This prepared flat membrane can effectively remove trace lipophilic organic pollutants from water. Structure of hybrid membrane is mainly observed by scanning electron microscope (SEM). Triolein dispersion by mechanical rabbling and ultrasound are investigated. Ultrasound can more effectively strengthen triolein dispersion than mechanical rabbling. Effect of casting membrane temperature (room temperature, 0℃) shows low temperature can help to forming smaller triolein droplets. In addition, interaction between triolein and CA belongs to physical mixing by the observation of FT-IR, accordingly triolein structure is not changed and adsorptive capacity for persistent organic pollutants is not affected. Triolein in hexane is analyzed by fluorometric measure. The results show that triolein is completely embedded into membrane, so it is impossible that triolein leaks into water in the process of the adsorption. |
