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连续流生物制氢反应器乙醇型发酵的运行特性
摘要点击 3454  全文点击 3121  投稿时间:2003-11-04  修订日期:2004-02-16
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中文关键词  生物制氢  乙醇型发酵  产氢能力  菌群
英文关键词  hydrogen bio-production  ethanol-type fermentation  hydrogen production rate  microbial community
作者单位
任南琪 哈尔滨工业大学市政环境工程学院 哈尔滨150090 
宫曼丽 哈尔滨工业大学市政环境工程学院 哈尔滨150090 
邢德峰 哈尔滨工业大学市政环境工程学院 哈尔滨150090 
中文摘要
      采用连续流搅拌槽式反应器(CSTR),利用厌氧活性污泥,在制糖废水产酸发酵过程的同时制取氢气.探讨了生物制氢反应器连续流稳定运行的工程控制参数.研究表明,在污泥接种量为15g/L、温度为35℃±1℃、COD容积负荷为40kg/(m3·d)、HRT为4h、系统pH、氧化还原电位(ORP)分别在4.6~4.9、-450~-470mV等条件下,可以实现连续流生物制氢反应系统乙醇型发酵的高效稳定运行.此时,液相末端发酵产物中乙醇和乙酸的含量占挥发酸总含量的80%以上,COD去除率22%~26%,气相中的氢气含量约为40%~58%,最大产氢能力为7.63m3/(m3·d).
英文摘要
      The natural response of a continuous stirred tank reactor (CSTR) for hydrogen bio-production using molasses wastewater as substrate was investigated. Emphasis was placed on assessing the operational controlling strategy on the stable operation of CSTR with high efficiency. It was found that at an initial biomass of 15g/L, an equilibrial microbial community in the ethanol-type fermentation and efficient stable operation of CSTR could be established with following conditions: temperature of 35℃±1℃, COD organic loading rate (OLR) of 40kg/(m3·d), hydraulic retention time (HRT) of 4h, pH value of 4.6~4.9 and oxidation reduction potential (ORP) of -450~-470mV. Following that, hydrogen production in the reactor was relatively stable. The observed maximal hydrogen bio-production rate was 7.63m3/(m3·d). The content of hydrogen in the biogas was about 40%~58%. COD removal rate was between 22%~26%. The total content of ethanol and acetic acid in the fermentative end products was above 80%.

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