| 燃煤飞灰对锅炉烟道气中Hg0的吸附特性 |
| 摘要点击 1714 全文点击 1721 投稿时间：2002-11-03 修订日期：2002-12-17 |
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| 中文关键词 燃煤飞灰 未燃炭 汞 吸附 |
| 英文关键词 fly ash unburned carbon Hg adsorption |
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| 中文摘要 |
| 在实验室模拟研究了燃煤飞灰颗粒组分对燃煤烟道气中气相Hg的吸附脱除特性.试验结果表明,Hg吸附量随飞灰烧失量的增长而增大,飞灰中不同类型介质的气相Hg吸附特性差异显著,其中未燃尽炭的Hg吸附性能最强,吸附剂BET比表面积与其Hg吸附量呈正相关关系.载气气相Hg浓度与Hg吸附量成非线性正相关关系,即Hg浓度为5×10-7时的Hg吸附量只有5×10-6的1/2.吸附温度与Hg吸附量呈较显著负相关关系.残炭表面的含氧官能团C=O有利于Hg的氧化和化学吸附.燃煤飞灰炭粒所具有的多孔隙结构和巨大比表面积有利于吸附脱除烟道气中Hg污染物. |
| 英文摘要 |
| Through the simulation experimentation, the Hg adsorption characteristics of fly ash in flue gas were studied carefully in laboratory. From the experiment results it was found that Hg adsorption capacity of different porous medium in fly ash was different obviously. Unburned carbon had higher Hg adsorption capacity. The surface-area of BET sorbent had positive correlation with Hg adsorption capacity. Hg concentration in blend gas had non-linearity relationship with Hg adsorption capacity. Hg adsorption capacity of 5×10-7 Hg concentration was only 1/2 compared to that of 5×10-6. Adsorption temperature had negative correlation with it. CO in unburnt carbon surface was beneficial to oxidation and chemic adsorption of Hg. It was obtained that the porous structure and huge surface-area of the unburned carbon was benefit to the Hg adsorption in flue gas. |
