| 二氧化钛颗粒的制备及其脱硫吸附性能 |
| 摘要点击 1076 全文点击 1680 投稿时间：2001-12-14 修订日期：2002-03-06 |
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| 中文关键词 二氧化钛 溶胶-凝胶法 物理吸附 固定床 |
| 英文关键词 titanium dioxide sol-gel physical sorption fixed-bed |
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| 中文摘要 |
| 采用溶胶-凝胶法(Sol-gel)在不同烧结温度(340℃,440℃,540℃,640℃)下制备了4种多孔TiO2颗粒,X射线衍射法(XRD)测得4种样品的晶相均为锐钛矿型.低温77K氮气吸附法计算4种样品的比表面积为79～124m2/g,平均孔径56.8～254.8 A.电子扫描电镜分析了样品的表面结构为多孔高孔隙率结构在固定床中对4种样品进行动态脱硫试验,试验结果表明烧结温度在540℃时制备的样品品质较好,每g TiO2颗粒可吸附38.9mg的SO2.以SG 540样品为例,研究了固定床中吸附温度,气相中SO2的浓度以及气体流速对其脱硫吸附性能的影响.与活性炭、沸石物理吸附剂比较,TiO2颗粒具有较高的脱硫吸附能力.FTIR红外光谱分析法,结合加热脱附试验的结果,得知TiO2颗粒吸附剂脱硫的机理主要是物理吸附. |
| 英文摘要 |
| Under different sintering temperatures(340℃,440℃,540℃,640℃), four TiO2 particles were prepared. The crystal types of all four samples were found to possess anatase structures by XRD. It was obtained by N2 experimental adsorption at low temperature (77K) that their surface areas and average pore size were between 79 and 124m2/g, 56.8 and 254.8 A respectively. The pore structure of TiO2 particles was characterized by scanning electron microscope (SEM). The tests of adsorption dynamics for FGD and the performance of SO2 removal were investigated in a fixed-bed system for different samples. The results show that SG540 sample which made at 540℃ sintering temperature had the most quality among the four samples. It can adsorb SO2 of 38.9mg for one gram SG540 sample. Different operating conditions for SG540 such as adsorption temperature, SO2 concentration in flue gas and the superficial velocity of flue gas were investigated. TiO2 particles for FGD had more efficiency than other physical sorbents such as active carbon and zeolite. The mechanism for SO2 removal was demonstrated by infrared (IR) spectroscopy and desorption test results to be mainly physical adsorption. |
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