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几种芳香化合物对苯并芘在泥浆反应器中降解的影响
摘要点击 1649  全文点击 1899  投稿时间:2001-11-07  修订日期:2002-01-02
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中文关键词  苯并芘  预处理  多环芳烃  共代谢  降解率
英文关键词  benzo[a]pyrene  pre exposure  PAHs  cometabolism  degradation rate
作者单位
巩宗强 中国科学院沈阳应用生态研究所 沈阳110016 
李培军 中国科学院沈阳应用生态研究所 沈阳110016 
王新 沈阳工业大学理学院 沈阳110023 
台培东 中国科学院沈阳应用生态研究所 沈阳110016 
张海荣 中国科学院沈阳应用生态研究所 沈阳110016 
中文摘要
      苯并芘在土壤中难于被生物降解,其降解方式通常以共代谢方式进行.本研究考查了几种多环芳烃及2种单环芳香化合物对苯并芘降解的影响.先把几种芳香化合物投入到供试无污染土壤中进行3d的预培养,然后向土壤中加入苯并芘并使土壤在三角瓶内形成泥浆系统,放在摇床上培养.42d的实验表明,用菲对土壤进行预处Ζ理消除了苯并芘的降解滞后期,并提高了苯并芘的降解率.蒽、芘未能改变苯并芘的降解模式,而苯并蒽则相对抑制了苯并芘的降解.水杨酸和邻苯二甲酸同样消除了苯并芘降解的滞后阶段,且促进了苯并芘的降解,但质量差别未对苯并芘的降解产生影响.
英文摘要
      Benzo(a)pyrene (BaP) can't be biodegraded in the soil easily, the degradation of BaP is know as a cometabolic process.This paper dealed with the effects of some polycyclic aromatic hydrocarbons (PAHs) and two kinds of monoaromatics on the degradation of BaP.The test soil was pre incubated with the aromatics for 3d and spiked with BaP stock solution, which eventually formed into slurry system in Erlenmeyer flasks and was incubated on rotary shaker.42 d experiment demonstrated that lag period in degradation process of BaP disappeared due to the preexposure to phenanthrene, and degradation rate of BaP was enhanced.On the contrary, degradation pattern of BaP was not obviously improved by the preexposure to anthracene or pyrene, and was even inhibited by benz(a)anthracene.The lag period also disappeared after the preexposure to salicylic acid or phthalic acid, and the degradation of BaP was accelerated by both monoaromatics, even though the impact of mass difference on the degradation of BaP was not detected.

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