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株洲市工业区大气中SO2转化速率的研究
摘要点击 742  全文点击 1389  投稿时间:1997-07-16  
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中文关键词  SO2  TSP  细粒子硫酸盐  转化速率  株洲市  工业区
英文关键词  sulphur dioxide  sulphate in fine particle  oxidation rate  Zhuzhou  industial region
作者单位
孙庆瑞 北京大学技术物理系, 北京 100871 
陈旦华 北京大学技术物理系, 北京 100871 
王美蓉 北京大学技术物理系, 北京 100871 
娄福成 株洲市环境监测站, 株洲市 412000 
中文摘要
      在湖南省株洲市工业区的下风向布点,同时测定大气中SO2的浓度、TSP和<0.25μm细粒子中SO42-的浓度。结果表明,大气中SO2浓度随着离污染源距离的增加迅速下降,和SO2相比,颗粒物中SO42-浓度随距离的增加而降低的程度要慢得多。同步测定的SO2浓度和细粒子SO42-浓度有显着的相关关系。根据风向、风速和新产生的细粒子中的SO42-浓度及大气中SO2的浓度计算了株洲教育学院处SO2的转化速率,春季湿度大,SO2转化速率也大,为4.8%/h,秋季湿度小,SO2的转化速率变低,为1.5%/h.春季中路铺SO2转化速率为3.1%/h.
英文摘要
      The sampling sites located downwind of Zhuzhou industrial region are Zhuzhou Education Institute,Zhonglupu and Heng Mountain.Gaseous SO2,SO42- in TSP and fine particle were measured at same time.The results point out that concentration of SO2 decreased rapidly with increasing distance of sampling site from emission source,but SO42- concentration in TSP and fine particle decreased much slowly than SO2 soncentration. A marked correlativity between the concentration of SO2 and SO42- measured simultaneously was observed.Based on wind velocity,the concentrations of SO2 and new formed SO42- in fine particle the oxidation rate of SO2 in Zhuzhou Education Institute was calculated.In spring,high oxidation rate of SO2 to be 4.8%/h was examined with RH>90%.In fall,oxidation rate of SO2 decreased to be 1.5%/h with about RH 50%.

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