| 异戊二烯与O3反应体系中有机氢过氧化物和H2O2的产率研究 |
| 摘要点击 723 全文点击 1386 投稿时间：1997-05-14 |
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| 中文关键词 异戊二烯 O3 双通道H2O2分析系统 有机氢过氧化物 H2O2 |
| 英文关键词 isoprene O3 Dual Channel H2O2 Analytical System organic hydroperoxides H2O2 |
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| 中文摘要 |
| 用双通道H2O2分析系统研究了室温条件下异戊二烯与O3气相暗反应体系中有机氢过氧化物和H2O2的产率。3次实验测得有机氢过氧化物的产率分别为3.8%、4.3%和3.9%,平均为4.0%;H2O2的产率分别为2.2%、1.6%和1.8%,平均为1.9%。探讨了异戊二稀与O3反应体系中有机氢过氧化物和H2O2的生成机理。 |
| 英文摘要 |
| The atmospheric reaction of isporene with O3 was simulated under the dark and room temperature in the 28.5L quartz reactor coupled with a Long Path Fourier Transform Infrared Spectrometer,while the Dual Channel H2O2 Analytical System was used to determine the production of organic hydroperoxides and H2O2.Yields measured respectively in the three repeated experiments are 3.8%,4.3% and 3.9% for organic hydroperoxides with the average of 4.0%,and 2.2%,1.6% and 1.8% for H2O2 with the average of 1.9%.The formation mechanisms of organic hydroperoxides and H2O2 were briefly discussed. |
