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燃煤流化床中N2O生成与分解的均相反应机理
摘要点击 653  全文点击 766  投稿时间:1993-11-30  
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中文关键词  流化床  燃烧    污染物
英文关键词  fluidized bed combustion  coal  nitrous oxide  reaction mechanism
作者单位
陈鸿伟  
金保升  
徐益谦  
刘坤磊  
中文摘要
      介绍由燃料氮生成N2O的主要途径是:NCO→NO→N2O+CO,NH+NO→N2O+H;分解N2O的主要反应是:N2O+H→N2十OH.分析了挥发分中的燃料氮成分、煤种、炉内温度、过量空气系数、分级与单级燃烧方式等因素对N2O排放的影响。
英文摘要
      he homogeneous reaction mechanisms of nitrous oxide formation and decomposition in the fluidized bed of coal combustion were studied,indicating that the baths of nitrous oxide (N2O) formation from nitrogen contained in fuel mainly include: NCO+NO→N2O+CO and NH+NO→N2O+H;and the main reaction of N2O decomposition are:N2O+H→N2+OH. An analysis was also made for the effects of the factors such as compeition of fuel-bounded nitrogen compounds in volatiles, kinds of coal, temperature in the fluidized bed, coefficient of excess air, number of singes, and the combustion pattern in a single sarge, on the emission of N2O from the fluidized bed coal combustor.

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