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用空气-硝酸活性炭-碱吸收法净化NOx废气
摘要点击 785  全文点击 884  投稿时间:1991-01-03  
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中文关键词  NOx  废气  草酸  喷淋吸收
英文关键词  NOx waste gas  absorption of NOx gas
作者单位
余龙醒 上海第二工业大学化工系 上海 200002 
中文摘要
      本文研究淀粉法生产草酸过程中排放的NOx废气的处理。先用空气做氧化剂,提高废气中NOx的氧化度,并经水吸收,可产生13%硝酸,其后在催化剂存在下,用此酸反复喷淋吸收NOx,使NOx转化为41%的硝酸。此酸可回收作为淀粉法生产草酸的原料。本文还研究了影响喷淋吸收的因素,如喷淋吸收剂的温度、浓度和喷淋速度以及催化剂品种、粒径大小,并得出喷淋吸收的最佳条件。
英文摘要
      In this artical, a new method for treating NOx containing waste gas generated from the process of oxalic acid production by starch method is introduced. Firstly, the oxidative extent of NOx gas is raised using air as oxidant. Then it is absorbed with water and 13% dilute nitric acid is formed. Secondly, the acid is used as an absorbent which is repeatedly sprayed over the NOx containing waste gas under the presence of catalyst, thus resulting in 41% nitric acid. The acid can be recovered as a material for the production of oxalic acid with "starch method". Through discussions on the factors which influence the effect of absorbent spray, such as temperature and concentration of the spraying absorbent, the velocity of spray, and tie variety and the sizes of the particles of the catalysts, the optimum conditions of the process are defined.

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