在Pt/Al2O3催化剂上异丁醇完全氧化动力学 |
摘要点击 1749 全文点击 1456 投稿时间:1989-05-31 |
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中文摘要 |
在Pt/Al2O3催化剂上用外循环无梯度反应器研究了异丁醇完全氧化动力学,异丁醇完全氧化动力学方程用异丁醇及氧吸附,CO2吸附阻碍的L-H模型描述,用正交设计法求出动力学方程中的参数,用脉冲法测定了异丁醇、氧及CO2的吸附热。 |
英文摘要 |
The kinetics of complete oxidation of iso-butyl alcohol on Pt/Al2O3 catalyst has been investigated by the external recirculation gradientless reactor. It i$ described by the L-H model of adsorption of iso-butyl alcohol and oxygen with inhibition of carbon dioxide. The parameters of the kinetics equation are estimated by the method of orthogonal design. The adsorption heat of iso-butyl alcohol, oxygen and carbon dioxide have been determined by the pulse method. |