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Co3O4/BiVO4复合阳极活化过一硫酸盐强化光电催化降解双酚A
摘要点击 40  全文点击 19  投稿时间:2017-11-04  修订日期:2018-02-28
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中文关键词  钒酸铋  Co3O4/BiVO4阳极  光电催化氧化  过一硫酸盐  双酚A
英文关键词  BiVO4  Co3O4/BiVO4 photoanode  photoelectrocatalytic  peroxymonosulfate  bisphenol A
作者单位E-mail
李蒋 大连工业大学轻工与化学工程学院, 大连 116034
中国科学院生态环境研究中心环境水质学实验室, 北京 100085 
liteng071520@163.com 
王雁 中国科学院生态环境研究中心环境水质学实验室, 北京 100085  
张秀芳 大连工业大学轻工与化学工程学院, 大连 116034 zhangxf@dlpu.edu.cn 
赵旭 中国科学院生态环境研究中心环境水质学实验室, 北京 100085 zhaoxu@rcees.ac.cn 
中文摘要
      采用静电纺丝法制备了Co3O4/BiVO4复合薄膜电极,并以之为光阳极,在过一硫酸盐(PMS)辅助作用下开展了光电催化降解双酚A研究.结果表明,PMS在可见光下可显著强化Co3O4/BiVO4复合阳极光电催化降解双酚A,在0.25 V外加偏压以及可见光照射下,当加入2 mmol·L-1 PMS时,双酚A在2 h内的降解效率为96%.降解动力学常数为0.4714 min-1.系统研究了PMS初始浓度、外加偏压对双酚A降解性能的影响.结果发现,双酚A在较低的PMS投加量和较低的外加偏压(0.25 V)下即可有效降解.采用电子自旋共振波谱仪鉴定体系的主要活性自由基为SO4·-和·OH.并进一步通过淬灭实验结果证明空穴、SO4·-和·OH起主要氧化作用.光电反应后的体系中未检测到金属离子溶出,可避免二次污染.
英文摘要
      A nanostructured Co3O4/BiVO4 composite photoanode was synthesized using a facile electrospinning method and applied to photoelectrochemical (PEC) degradation of bisphenol A (BPA) with the assistance of peroxymonosulfate (PMS). Results show that PMS obviously enhanced the photoelectrocatalytic degradation of BPA by the Co3O4/BiVO4 composite photoanode. When at 0.25 V bias potential and visible light irradiation, with 2 mmol·L-1 PMS addition, 96% of BPA was removed within 2 h, and the corresponding kinetic constant was 0.4714 min-1. The effects of initial PMS concentration and bias potential on the BPA degradation were studied. Results show that BPA could be efficiently degraded at lower PMS concentrations and lower bias potentials. SO4·- and·OH were identified as the primary free radicals using an electron spin resonance spectrometer. Free radical quenching experiments were carried out, and the photogenerated hole, SO4·-, and·OH proved to be responsible for the BPA oxidation. There was no metal ion leaching detected in the solution after the reactions, which means the secondary pollution could be avoided.

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