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大型炼锌厂周边土壤及蔬菜的汞污染评价及来源分析
摘要点击 2854  全文点击 1256  投稿时间:2012-04-09  修订日期:2012-05-20
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中文关键词  锌冶炼  大气汞  土壤  蔬菜  汞含量
英文关键词  zinc smelting  mercury pollution  soil  vegetable  mercury content
作者单位E-mail
刘芳 北京科技大学土木与环境工程学院,北京 100083 liufang20100277@163.com 
王书肖 清华大学环境学院,环境模拟与污染控制国家重点联合实验室,北京 100084 shxwang@tsinghua.edu.cn 
吴清茹 清华大学环境学院,环境模拟与污染控制国家重点联合实验室,北京 100084  
林海 北京科技大学土木与环境工程学院,北京 100083  
中文摘要
      采集某大型炼锌厂周边的耕种土壤及蔬菜样品,分析其汞含量,并采用单项污染指数法及相关标准对土壤和蔬菜的汞污染状况进行了评价.结果表明,炼锌厂周边的耕种土壤和蔬菜都受到了不同程度的汞污染.土壤样品汞的超标率为78%,其中污染最严重区域土壤中的汞浓度是背景点土壤汞浓度的29倍,已达到重度污染程度.所有蔬菜样品的汞含量超过无公害蔬菜重金属限量指标,最大超标64.5倍,平均超标25.4倍.85%的蔬菜样品叶片中汞含量明显高于根部汞含量,说明叶片中的汞主要来自于大气; 蔬菜根部汞含量与土壤汞含量明显线性相关,说明根部的汞主要来自于土壤.炼锌厂汞排放对其周边土壤和蔬菜的汞污染均有显著的影响.
英文摘要
      The farming soil and vegetable samples around a large-scale zinc smelter were collected for mercury content analyses, and the single pollution index method with relevant regulations was used to evaluate the pollution status of sampled soils and vegetables. The results indicated that the surface soil and vegetables were polluted with mercury to different extent. Of the soil samples, 78% exceeded the national standard. The mercury concentration in the most severely contaminated area was 29 times higher than the background concentration, reaching the severe pollution degree. The mercury concentration in all vegetable samples exceeded the standard of non-pollution vegetables. Mercury concentration, in the most severely polluted vegetables were 64.5 times of the standard, and averagely the mercury concentration in the vegetable samples was 25.4 times of the standard. For 85% of the vegetable samples, the mercury concentration, of leaves were significantly higher than that of roots, which implies that the mercury in leaves mainly came from the atmosphere. The mercury concentrations in vegetable roots were significantly correlated with that in soils, indicating the mercury in roots was mainly from soil. The mercury emissions from the zinc smelter have obvious impacts on the surrounding soils and vegetables.

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