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氧化强化对氢氧化钙原位固磷效果的影响
摘要点击 1616  全文点击 521  投稿时间:2020-07-11  修订日期:2020-07-31
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中文关键词  原位固定技术  内源磷  氧化  固定  强化
英文关键词  In-situ immobilization technique  internal phosphorus  oxidation  immobilization  strengthening
作者单位E-mail
徐楚天 苏州科技大学环境与工程学院, 苏州 215009 xctdrj@163.com 
李大鹏 苏州科技大学环境与工程学院, 苏州 215009 ustsldp@163.com 
岳薇 苏州科技大学环境与工程学院, 苏州 215009  
吴宇涵 苏州科技大学环境与工程学院, 苏州 215009  
孙培荣 苏州科技大学环境与工程学院, 苏州 215009  
汤尧禹 苏州科技大学环境与工程学院, 苏州 215009  
黄勇 苏州科技大学环境与工程学院, 苏州 215009  
中文摘要
      将氢氧化钙[Ca(OH)2]和过氧化氢(H2O2)以梅花散点的方式注射到底泥中,考察两者联用对内源磷的控制效果.结果表明,单独投加Ca(OH)2可以有效固定沉积物-水界面(SWI)以下约20 mm沉积物中约90%的内源磷,但同时会加剧20 mm以下沉积物的厌氧环境,导致沉积物中稳定态磷向易释放态磷转化,造成潜在活性磷的累积;而H2O2的加入极大地降低了Ca(OH)2投加后深层沉积物潜在活性磷富集的风险,并明显提高了Ca(OH)2在沉积物中的纵向扩散深度,其影响范围可以达到SWI以下0~40 mm;但40 mm以下沉积物影响并不明显;这主要归因于氧化剂的投加导致氧化还原电位提高了近18倍.底泥内源磷形态变化也证实了氧化剂投加对磷的良好固定效果.与对照实验相比,SWI以下0~20 mm沉积物中易释放态磷含量明显降低,同时沉积物中Ca-P含量增加了约10%.但随着底泥深度增加,易释放态磷减少量逐渐降低,Ca-P的增加也逐渐变缓.
英文摘要
      In this research, calcium hydroxide[Ca(OH)2] and hydrogen peroxide (H2O2) were injected into the bottom mud in the form of plum blossom scatterers to investigate the effect on the control of endogenous phosphorus. The results showed that Ca(OH)2 used singly effectively immobilized in the order of 90% of endogenous phosphorus approximately 20 mm below the sediment-water interface (SWI); however, at the same time, the anaerobic environment was enhanced, resulting in the transformation of stable phosphorus to easily released phosphorus and the accumulation of potential active phosphorus. Nevertheless, the addition of H2O2 greatly reduced the amount of potential active phosphorus in deep sediments after adding Ca(OH)2. The vertical diffusion depth of Ca(OH)2 in the sediments was significantly increased, having an influence across the depth range of 0-40mm below the SWI; the improvement at depths greater than 40 mm was not notable, which was mainly attributed to an 18-fold increase of redox potential due to the addition of the oxidant. The change of phosphorus forms in the sediment also demonstrated the excellent immobilization effect of the oxidant on phosphorus. In the 0-20 mm layer, the content of readily released phosphorus decreased significantly, while compared with a control test, Ca-P increased by approximately 10%. However, at greater depths, the amount of easily released phosphorus decreased and the rate of Ca-P increase gradually slowed.

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