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金泽水库上游来水及库区水质变化时空分布特征
摘要点击 1854  全文点击 644  投稿时间:2019-02-16  修订日期:2019-04-21
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中文关键词  金泽水库  太浦河  荧光溶解性有机质(FDOM)  主成分分析  时空分布
英文关键词  Jinze Reservoir  Taipu River  fluorescent dissolved organic matter(FDOM)  principal component analysis  spatio-temporal distribution
作者单位E-mail
刘明坤 上海交通大学生命科学技术学院, 微生物代谢国家重点实验室, 上海 200240 liumingkun@sjtu.edu.cn 
童俊 上海市供水调度监测中心, 上海 200080  
胡波 上海市供水调度监测中心, 上海 200080  
朱慧峰 上海市供水调度监测中心, 上海 200080  
白晓慧 上海交通大学生命科学技术学院, 微生物代谢国家重点实验室, 上海 200240 xhbai@sjtu.edu.cn 
中文摘要
      金泽水库是上海西南五区的主要饮用水源,上游太浦河来水及库区水质变化对水库运行和相应供水系统供水水质有重要影响.基于常规水质指标应用主成分分析法评价了不同季节金泽水库上游来水及库区水质变化;利用平行因子(PARAFAC)分析了金泽水库上游来水及库区水中荧光溶解性有机质(FDOM)组成结构及分布特征;通过相关性分析分析了水体荧光强度与常规水质指标间的关系.结果表明,金泽水库上游来水及库区冬季水质最差,库外断面水质受外源污染逐步恶化,经过库区生态净化作用后水质有所提升;水体FDOM主要由类蛋白类和类腐殖质类组分构成,类蛋白物质为主要组分,各组分呈现出明显的时空分布特征,外源污染是影响库外断面FDOM总荧光强度的主要因素,生态环境是影响库内FDOM总荧光强度季节性波动的主要因素.FDOM总荧光强度呈现上游低下游高的趋势,与水中NH4+-N、石油类、TOC、氯化物和硫酸盐含量显著相关,通过检测FDOM总荧光强度可实现对水体水质的快速分析并发挥预警和指示作用.
英文摘要
      Jinze Reservoir is the main drinking water source for southwest Shanghai. The water quality in the upstream Taipu River and reservoir have an important impact on the performance of the reservoir and the quality of the water supply. Conventional water parameters were analyzed using principal component analysis (PCA) to evaluate seasonal variations in water quality in the upper reaches of Jinze Reservoir. The parallel factor (PARAFAC) was also used to analyze water-soluble dissolved organic matter (FDOM) in the upstream waters and reservoir area. Furthermore, the relationships between water fluorescence intensity and conventional water quality indicators were analyzed using correlation analysis. The results show that water quality in the upper reaches of Jinze Reservoir is worst in the winter, and water quality gradually deteriorates in the outer sections of the reservoir due to external pollution inputs. Ecological purification within the reservoir area functions to improve water quality. The water body FDOM content is mainly composed of proteinoids and humus. Protein-like substances are the main components of this material, and each component exhibits clear spatial and temporal distribution characteristics. External pollution is the main factor affecting the total fluorescence intensity of the FDOM outside of the reservoir. In the reservoir, the ecological environment affects the total fluorescence intensity of FDOM. The total fluorescence intensity of FDOM showed an increasing downstream spatial trend, which was significantly correlated with NH4+-N, petroleum, TOC, chloride, and sulfate content in the water. By detecting the total fluorescence intensity of FDOM, the rapid analysis of water quality can be achieved to inform early warning.

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