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水解酸化/AO组合工艺处理印染废水色度去除与脱氮性能
摘要点击 1509  全文点击 651  投稿时间:2018-04-05  修订日期:2018-06-11
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中文关键词  水解酸化  缺氧/好氧  色度  硝化抑制  印染废水
英文关键词  hydrolysis/acidification  anoxic/aerobic  color  nitrification inhibition  dyeing wastewater
作者单位E-mail
顾梦琪 清华大学深圳研究生院, 深圳市环境微生物利用与安全控制重点实验室, 深圳 518055 947781795@qq.com 
尹启东 清华大学深圳研究生院, 深圳市环境微生物利用与安全控制重点实验室, 深圳 518055  
刘爱科 清华大学深圳研究生院, 深圳市环境微生物利用与安全控制重点实验室, 深圳 518055  
吴光学 清华大学深圳研究生院, 深圳市环境微生物利用与安全控制重点实验室, 深圳 518055 wu.guangxue@sz.tsinghua.edu.cn 
中文摘要
      偶氮染料是一种具有稳定化学结构的活性染料,排放至环境中会损害人体健康和影响水生生物生长.利用水解酸化/AO组合工艺处理含偶氮染料活性艳红X-3B(RR2)的印染废水,重点考察了色度去除和脱氮性能.组合工艺可有效去除色度、化学需氧量(COD)和氨氮,去除率分别为71.0%、92.2%和83.5%.水解酸化反应器中主要偶氮染料降解菌为Desulfovibrio;AO反应器中硝化菌主要为Nitrospira,反硝化菌为ThaueraDechloromonas.水解酸化温度从25℃提高至35℃,色度去除率提高141.2%;25℃时COD浓度从200 mg·L-1提高至800 mg·L-1,色度去除率提高208.9%.AO反应器出现亚硝酸盐积累现象,亚硝化率为73.8%.染料RR2对硝化没有抑制作用,而苯胺会抑制硝化;当苯胺浓度超过6 mg·L-1时,氨氮氧化速率最低.
英文摘要
      Azo dye is a type of reactive dyes with a stable structure. Its discharge into the environment affects the human health and growth of aquatic organisms. The color and nitrogen removal through an integrated hydrolysis/acidification and anoxic/aerobic (AO) process for the treatment of wastewater containing reactive red 2 (RR2) was investigated. The color, chemical oxygen demand (COD), and ammonia nitrogen were removed efficiently, with removal efficiencies of 71.0%, 92.2%, and 83.5%, respectively. The dominant azo dye degradation bacterium in the hydrolysis/acidification reactor was Desulfovibrio. The dominant nitrifying bacterium in the AO reactor was Nitrospira, while the denitrifying bacteria were Thauera and Dechloromonas. When increasing the hydrolysis/acidification temperature from 25℃ to 35℃, the color removal efficiency improved by 141.2%. When the concentration of COD increased from 200 mg·L-1 to 800 mg·L-1 at 25℃, the color removal efficiency improved by 208.9%. Nitrite accumulation occurred in the AO reactor with a nitritation efficiency of 73.8%. The RR2 did not inhibit the nitrification, while aniline inhibited the nitrification. At an aniline concentration of 6 mg·L-1, the ammonia oxidation was the slowest.

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