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生物膜短程硝化系统的恢复及其转化为CANON工艺的过程
摘要点击 2504  全文点击 817  投稿时间:2016-09-28  修订日期:2016-11-12
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中文关键词  生物膜  短程硝化  亚硝酸化率  CANON工艺  游离氨  厌氧氨氧化
英文关键词  biofilm  short-cut nitrification  nitrite accumulation rate  CANON process  free ammonia(FA)  anaerobic ammonium oxidation(ANAMMOX)
作者单位E-mail
付昆明 北京建筑大学环境与能源工程学院, 城市雨水系统与水环境省部共建教育部重点实验室, 北京 100044 fukunming@163.com 
周厚田 北京建筑大学环境与能源工程学院, 城市雨水系统与水环境省部共建教育部重点实验室, 北京 100044  
苏雪莹 北京建筑大学环境与能源工程学院, 城市雨水系统与水环境省部共建教育部重点实验室, 北京 100044  
王会芳 北京建筑大学环境与能源工程学院, 城市雨水系统与水环境省部共建教育部重点实验室, 北京 100044  
中文摘要
      在温度为30℃±1℃条件下,以改性聚乙烯为填料,人工配置无机NH4+-N废水为进水,研究生物膜短程硝化系统的恢复过程.短程硝化首先通过过量曝气破坏,使NOB适应高浓度游离氨后,在连续曝气条件下,DO控制在0.5 mg·L-1以下,FA控制在1.5 mg·L-1以上,维持反应器运行83 d未实现短程硝化,84 d改连续曝气为间歇曝气,出现NO2--N积累现象,142 d再次验证这一规律.随着反应器的运行,生物膜系统中为ANAMMOX菌提供了生存环境,厌氧氨氧化作用产生,短程硝化系统逐步转化为CANON工艺,并逐渐增加进水NH4+-N浓度和进水流量,反应器的TN去除率与TN去除负荷逐渐提高.当反应器运行至450 d,TN去除率达到64.03%,去除负荷为2.52 kg·(m3·d)-1.因此,一旦NOB适应了高浓度的游离氨,生物膜系统的短程硝化恢复不易实现,但间歇曝气是一个有效的方法,随着反应器的连续运行,短程硝化工艺最终转化为CANON工艺,而且,这一转变进一步强化了短程硝化的稳定性.
英文摘要
      A short-cut nitrification process with modified polyethylene as carrier was operated to investigate the biofilm short-cut nitrification recovery using synthetic inorganic ammonia-rich wastewater as influent at 30℃ ±1℃. The short-cut nitrification was destroyed first by excessive aeration, and it was not built in 83 days under the condition of continuous aeration with DO less than 0.5 mg·L-1 and free ammonia (FA) more than 1.5 mg·L-1, which are very beneficial to short-cut nitrification. However,short-cut nitrification was realized by changing continuous aeration to intermittent aeration on 84th day, and it was proved again on 142nd day. After that, biofilm system provided a living environment for ANAMMOX bacteria, anaerobic ammonia oxidation occurred, and the biofilm short-cut nitrification process was gradually transformed into CANON process. As the load of influent and aeration increased, the total nitrogen removal efficiency and removal load increased, and the total nitrogen removal load could reach up to 2.52 kg·(m3·d)-1. Finally, in the 3rd stage, ΔNO3--N/ΔTN was 0.10 on average, which means stabe short-cut nitrification in the CANON process. Therefore, once NOB was adapted to FA, it would be not very easy to recover short-cut nitrification, while intermittent aeration was an effective way, and the nitriation process would be finally transformed into CANON process, which would further improve the short-cut nitrification stability.

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