| 太原市耕地土壤PAHs的含量、分布、源解析与风险评价 |
| 摘要点击 1259 全文点击 410 投稿时间：2022-06-25 修订日期：2022-10-19 |
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| 中文关键词 耕地 多环芳烃(PAHs) 太原市 源解析 风险评价 |
| 英文关键词 arable soils polycyclic aromatic hydrocarbons (PAHs) Taiyuan source analysis risk assessment |
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| 中文摘要 |
| 为研究太原市耕地土壤中多环芳烃(PAHs)的含量、空间分布特征、来源与健康风险,采集了太原市22个耕地土壤样本,通过GC-MS分析土壤中PAHs的含量,使用诊断比率法与正定矩阵因子分解(PMF)模型分析土壤PAHs的来源,使用增量终生致癌风险模型分析土壤的健康风险.结果表明,太原市耕地土壤(干重)中Σ21PAHs和Σ16PAHs含量平均值分别为934.6 ng ·g-1和787.7 ng ·g-1,土壤中PAHs含量低于GB 15168-2018规定的农用地土壤污染风险筛选值.工业区、丘陵区和污灌区分别有约60%、13%和33%的样点的PAHs含量超过了1000 ng ·g-1.空间分布显示耕地土壤PAHs含量高的区域集中在工业区; 诊断比率显示煤炭和生物质燃烧与交通排放是太原市耕地土壤中PAHs污染的主要来源; PMF模型模拟结果表明,耕地土壤中PAHs的来源和贡献率为煤炭和生物质燃烧源(59%)、交通源(22%)和炼焦源(19%).风险评价结果表明太原市耕地土壤普遍具有高致癌风险,应当引起人们的关注. |
| 英文摘要 |
| PAHs (polycyclic aromatic hydrocarbons) accumulated in arable soils have significant impacts on farmland quality and human health, which has attracted wide attention from scientists and the public. A total of 22 arable soil samples were collected from Taiyuan, an old industrial city, including three districts (industrial zones, hilly areas, and sewage irrigation area), and the contents of 21 PAHs were detected using the GC-MS method. The sources of PAHs in soils were analyzed using the diagnostic ratios (DRs) method and positive matrix factorization (PMF) model, and the soil health risks were analyzed using the incremental lifetime cancer risk (ILCR) model. The results indicated that the average concentrations of Σ21PAHs and Σ16PAHs in arable soils of Taiyuan were 934.6 ng·g-1 and 787.7 ng·g-1, respectively, which were lower than the soil pollution risk screening value of agricultural land stipulated in GB 15168-2018. 3-5 rings PAHs were the dominant components, accounting for~90% of the Σ21PAHs. Approximately 60% of sites in industrial zones, 13% in hilly areas, and 33% in the sewage irrigation area had high PAHs contents larger than 1000 ng·g-1. The spatial distribution of PAHs showed that more severe PAHs pollution in the soil occurred in industrial areas than that in the other two districts. The DRs suggested that the combustion of coals, bio-masses, and traffic emissions were the dominant sources for PAHs pollution in arable soils in Taiyuan. The simulation results of the PMF model indicated that the sources and contribution rates of PAHs in cultivated soils were coal and biomass burning sources (59%), traffic sources (22%), and coking sources (19%). The risk assessment confirmed that the arable soils in Taiyuan had high potential carcinogenic risks; thus, more attention should be paid to the PAHs pollutions in arable soils. |
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