| 基于响应曲面法的臭氧生成敏感性分析 |
| 摘要点击 1749 全文点击 460 投稿时间：2022-08-12 修订日期：2022-09-30 |
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| 中文关键词 臭氧(O3) 响应曲面 O3敏感性 盒子模式 一氧化碳(CO) 挥发性有机物(VOCs) |
| 英文关键词 ozone(O3) response surface O3 sensitivity box model carbon monoxide(CO) volatile organic compounds(VOCs) |
| 作者 | 单位 | E-mail | | 朱禹寰 | 兰州大学大气科学学院, 半干旱气候变化教育部重点实验室, 兰州 730000 | zhuyh20@lzu.edu.cn | | 陈冰 | 聚光科技(杭州)股份有限公司, 杭州 310000 | | | 张雅铷 | 兰州大学大气科学学院, 半干旱气候变化教育部重点实验室, 兰州 730000 | | | 刘晓 | 兰州大学大气科学学院, 半干旱气候变化教育部重点实验室, 兰州 730000 | | | 李光耀 | 兰州大学大气科学学院, 半干旱气候变化教育部重点实验室, 兰州 730000 | | | 舍静 | 兰州大学大气科学学院, 半干旱气候变化教育部重点实验室, 兰州 730000 | | | 陈强 | 兰州大学大气科学学院, 半干旱气候变化教育部重点实验室, 兰州 730000 | chenqqh@lzu.edu.cn |
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| 中文摘要 |
| 准确判断臭氧（O3）生成敏感性对O3污染成因分析和防控对策的制定至关重要.首次利用响应曲面方法设计最优试验方案，基于盒子模式模拟结果，快速量化O3对其前体物变化的响应.结果表明，CO对O3有正贡献，NOx和VOCs与O3呈现显著非线性关系，当φ（VOCs）与［φ（NOx）-13.75］比值大于4.17时，为NOx控制区，小于4.17时，为VOCs控制区；烯烃为影响O3生成的关键VOCs组分，当φ（烯烃）与［φ（NOx）-15］比值小于1.10且φ（烯烃）<35×10-9时，烯烃有利于O3的生成.响应曲面法在多因素和其交互作用对O3生成影响的研究中取得了良好效果，为高效判断O3敏感性提供了新的思路和方法. |
| 英文摘要 |
| Identifying the nonlinear relationship between O3 and its precursors accurately plays an important role for the policy-making of O3 pollution control. In this study, the response surface methodology based on the box model simulation was used to quickly and efficiently quantify the O3 response to their precursors with the optimal experimental design. The results showed that CO had a positive contribution to ozone generation, whereas NOx and VOCs had a significant nonlinear relationship with O3. When the ratio of φ(VOCs) to[φ(NOx)-13.75] was greater than 4.17, the ozone formation regime was NOx-limited and became VOCs-limited when the ratio was less than 4.17. Olefin was the key VOCs' component to affect the formation of O3; when the radio of φ(olefin) to[φ(NOx)-15] was less than 1.10 and the value of the φ(olefin) was less than 35×10-9, olefin went far towards generating O3. Response surface methodology demonstrated that it can be well used to explore the influence of multiple factors and their interactions on O3 formation and provides a new approach for efficient O3 sensitivity analysis. |
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