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部分亚硝化-厌氧氨氧化协同反硝化处理生活污水脱氮除碳
摘要点击 2211  全文点击 727  投稿时间:2021-01-25  修订日期:2021-03-28
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中文关键词  间歇曝气  温度  部分亚硝化  厌氧氨氧化(ANAMMOX)  反硝化  C/N
英文关键词  intermittent aeration  temperature  partial nitritation  anaerobic ammonium oxidation(ANAMMOX)  denitrification  C/N
作者单位E-mail
秦彦荣 兰州交通大学环境与市政工程学院, 兰州 730070
甘肃省黄河水环境重点实验室, 兰州 730070
甘肃省污水处理行业技术中心, 兰州 730070 
1249354392@qq.com 
袁忠玲 兰州交通大学环境与市政工程学院, 兰州 730070
甘肃省黄河水环境重点实验室, 兰州 730070
甘肃省污水处理行业技术中心, 兰州 730070 
 
张明 兰州交通大学环境与市政工程学院, 兰州 730070
甘肃省黄河水环境重点实验室, 兰州 730070
甘肃省污水处理行业技术中心, 兰州 730070 
 
张民安 兰州交通大学环境与市政工程学院, 兰州 730070
甘肃省黄河水环境重点实验室, 兰州 730070
甘肃省污水处理行业技术中心, 兰州 730070 
 
刘安迪 兰州交通大学环境与市政工程学院, 兰州 730070
甘肃省黄河水环境重点实验室, 兰州 730070
甘肃省污水处理行业技术中心, 兰州 730070 
 
付雪 兰州交通大学环境与市政工程学院, 兰州 730070
甘肃省黄河水环境重点实验室, 兰州 730070
甘肃省污水处理行业技术中心, 兰州 730070 
 
马娟 兰州交通大学环境与市政工程学院, 兰州 730070
甘肃省黄河水环境重点实验室, 兰州 730070
甘肃省污水处理行业技术中心, 兰州 730070 
 
陈永志 兰州交通大学环境与市政工程学院, 兰州 730070
甘肃省黄河水环境重点实验室, 兰州 730070
甘肃省污水处理行业技术中心, 兰州 730070 
476411589@qq.com 
中文摘要
      采用SBR-ASBR组合工艺处理实际生活污水,SBR中考察缺氧/好氧时间比及温度对部分亚硝化(partial nitritation,PN)的作用,ASBR中研究COD/NO2--N(C/N)对厌氧氨氧化(anaerobic ammonium oxidation,ANAMMOX)协同反硝化脱氮除碳的影响.①控制温度为25℃,在缺氧/好氧时间比为30 min:30 min,单周期交替3次时,NO2--N积累率(NiAR)于第22 d为98.06%,比亚硝态氮产生速率(SNiPR,以N/VSS计)为0.28g·(g·d)-1,同步硝化反硝化去除的TN和COD分别为12.29 mg·L-1和110.36mg·L-1.②在缺氧/好氧时间比为30 min:30 min下,温度为15℃时,丝状菌大量繁殖,污泥活性和沉降性变差;温度为30℃时,NH4+-N转化为NO2--N比例为86.83%,造成出水NH4+-N浓度过低,不能为厌氧氨氧化提供合适基质浓度;温度为25℃时,出水NH4+-N和NO2--N浓度分别为31.58 mg·L-1和35.04mg·L-1,匹配厌氧氨氧化基质比.③组合工艺脱氮性能良好,出水TN、NH4+-N和COD浓度分别稳定在13.13、4.83和69.96mg·L-1,去除率分别为83.10%、93.64%和75.11%.调节ASBR进水C/N为2.5、2.0和1.5时,C/N为2.0时厌氧氨氧化协同反硝化脱氮除碳性能最佳,出水NH4+-N、NO2--N、NO3--N和COD分别为0.09、0.25、1.04和32.73mg·L-1.
英文摘要
      A sequencing batch reactor-anaerobic sequencing batch reactor(SBR-ASBR) process was used to treat domestic sewage. In the SBR, the effects of the anoxic/aerobic time ratio and temperature on the realization of partial nitritation(PN) were investigated. In the ASBR, the effects of different COD/NO2--N(C/N) ratios on the removal of nitrogen and carbon using anaerobic ammonia oxidation(ANAMMOX) and denitrification were studied. The results illustrated that:① After three single cycles and on the 22nd day, the NO2--N accumulation rate(NiAR) was 98.06%, and the nitrate nitrogen generation rate(SNiPR, calculated as N/VSS) was 0.28g·(g·d)-1, and simultaneous nitrification and denitrification removal the TN and COD were 12.29 and 110.36mg·L-1, respectively(temperature=25℃, anoxic/aerobic time ratio=30 min:30 min). ② At an anoxic/aerobic time ratio of 30 min:30 min, the filamentous sludge bulked, the sludge activity decreased, and sludge settleability was poor at 15℃. Furthermore, the conversion rate of NH4+-N to NO2--N was 86.83%, indicating that the effluent NH4+-N concentration was too low to provide suitable matrix concentrations for ANAMMOX at 30℃. The effluent concentrations of NH4+-N and NO2--N were 31.58 mg·L-1 and 35.04mg·L-1, respectively, matching the ratio of the ANAMMOX substrate at 25℃. ③ The SBR-ASBR combined process showed good denitrification performance; the effluent TN, NH4+-N, and COD concentrations were stable at 13.13, 4.83, and 69.96mg·L-1, respectively, and the removal rates were 83.10%, 93.64%, and 75.11%, respectively. When the influent C/N of the ASBR was 2.5, 2.0, and 1.5, respectively, anaerobic ammonia oxidation and denitrification showed the best performance with respect to nitrogen and carbon removal with a C/N of 2.0. The effluent NH4+-N, NO2--N, NO3--N, and COD were 0.09, 0.25, 1.04, and 32.73 mg·L-1, respectively.

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