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催化铁强化低碳废水生物反硝化过程的探讨
摘要点击 2481  全文点击 1052  投稿时间:2013-11-19  修订日期:2013-12-30
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中文关键词  反硝化  低碳氮比  硝酸根转化  催化铁  氧化亚氮  氧化还原电位
英文关键词  denitrification  under low carbon-nitrogen ratio  nitrate transformation  catalytic iron  nitrous oxide  oxidation-reduction potential
作者单位E-mail
王梦月 同济大学污染控制与资源化研究国家重点实验室, 上海 200092 wangmy_1988@126.com 
马鲁铭 同济大学污染控制与资源化研究国家重点实验室, 上海 200092 lumingma@tongji.edu.cn 
中文摘要
      研究了低碳氮比条件下催化铁耦合生物反硝化的脱氮效率以及N2O产生. 结果表明,相对常规低碳氮比反硝化,催化铁耦合组能大大提高硝酸根的转化率,但产生亚硝态氮积累,总氮去除率变化不大. 耦合组N2O释放量高于常规生物对照组,源于亚铁氧化物与亚硝酸根的化学反应,但最高累积量小于8%,且可继续生物还原为N2. 催化铁可以消除体系的溶解氧和降低氧化还原电位,对维持缺氧反硝化环境有利.
英文摘要
      The nitrogen removal efficiency and N2O production during the process of coupling catalytic iron and biological denitrification for low C/N ratio wastewater were studied. The results showed that biological denitrification coupled with catalytic iron could significantly improve nitrate transforming efficiency, but led to nitrite accumulation, resulting in little difference in total nitrogen removal efficiency, compared with traditional biological denitrification. N2O production from the catalytic iron group was obviously higher than the traditional control group, among which chemical reaction between ferrous oxide and nitrite had great contribution. However, the highest amount of accumulated N2O was less than 8% of the removed nitrate, and N2O was further reduced to N2 by microorganisms. Furthermore, catalytic iron group could eliminate dissolved oxygen and lower the oxidation reduction potential, which is beneficial for keeping anoxic conditions during denitrification.

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