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微生物燃料电池利用甘薯燃料乙醇废水产电的研究
摘要点击 2095  全文点击 1000  投稿时间:2009-12-18  修订日期:2010-03-24
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中文关键词  甘薯燃料乙醇废水  微生物燃料电池  产电;磷酸缓冲液;废水浓度
英文关键词  sweet potato fuel ethanol wastewater  microbial fuel cell(MFC)  electricity generation  phosphate buffer solution  wastewater concentration
作者单位
蔡小波 中国科学院成都生物研究所成都610041中国科学院研究生院北京100049 
杨毅 中国科学院成都生物研究所成都610041中国科学院研究生院北京100049 
孙彦平 中国科学院成都生物研究所成都610041中国科学院研究生院北京100049 
张良 中国科学院成都生物研究所成都610041中国科学院研究生院北京100049 
肖瑶 中国科学院成都生物研究所成都610041中国科学院研究生院北京100049 
赵海 中国科学院成都生物研究所成都610041 
中文摘要
      利用空气阴极微生物燃料电池(MFC)处理甘薯燃料乙醇废水,以COD为5000 mg/L的废水做底物,获得的最大电功率密度为334.1 mW/m2, 库仑效率(CE)为10.1%, COD去除率为92.2%.实验进一步考察了磷酸缓冲液(PBS)浓度和废水浓度对MFC产电性能的影响.PBS含量从50 mmol/L增加到200 mmol/L,MFC输出的最大电功率密度提高了33.4%, CE增加26.0%,但PBS对废水的COD去除率影响不大.含50 mmol/L PBS的废水COD从625 mg/L增加到10000 mg/L, COD去除率和MFC输出的最大电功率密度在废水浓度为5000 mg/L处均获得最大值,但CE值有降低的趋势,从28.9%变化至10.3%.这些结果表明,MFC可以在处理甘薯燃料乙醇废水的同时获得电能;增大PBS浓度能提高MFC的产电性能;MFC输出的最大电功率密度随废水COD增加而增大,但废水浓度过高会引起酸化使MFC产电性能下降.
英文摘要
      Air cathode microbial fuel cell (MFC) were investigated for electricity production from sweet potato fuel ethanol wastewater containing 5000 mg/L of chemical oxygen demand (COD). Maximum power density of 334.1 mW/m2, coulombic efficiency (CE) of 10.1% and COD removal efficiency of 92.2% were approached. The effect of phosphate buffer solution (PBS) and COD concentration on the performance of MFC was further examined. The addition of PBS from 50 mmol/L to 200 mmol/L increased the maximum power density and CE by 33.4% and 26.0%, respectively. However, the COD removal efficiency was not relative to PBS concentration in the wastewater. When the COD increased from 625 mg/L to 10000 mg/L, the maximum value of COD removal efficiency and the maximum power density were gained at the wastewater strength of 5000 mg/L. But the CE ranged from 28.9% to 10.3% with a decreasing trend. These results demonstrate that sweet potato fuel ethanol wastewater can be used for electricity generation in MFC while at the same time achieving wastewater treatment. The increasing of PBS concentration can improve the power generation of MFC. The maximum power density of MFC increases with the rise of COD concentration, but the electricity generation will decrease for the acidification of high wastewater concentration.

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