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Fe2+浓度对生物产氢动力学的影响
摘要点击 3046  全文点击 2255  投稿时间:2007-09-20  修订日期:2007-12-18
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中文关键词  Fe2+  生物产氢  动力学  比产氢率
英文关键词  Fe2+  biohydrogen production  kinetics  hydrogen yield
作者单位
万伟 清华大学核能与新能源技术研究院环境技术研究室, 北京 100084 
王建龙 清华大学核能与新能源技术研究院环境技术研究室, 北京 100084 
中文摘要
      研究了Fe2+在0~1 500 mg/L 范围内对混合细菌发酵产氢动力学的影响.结果表明,以葡萄糖为底物,在35℃ 和初始pH为7.0时,当Fe2+浓度为0~300 mg/L 时,混合细菌发酵葡萄糖的最大累积产氢量和平均产氢速率都随着Fe2+浓度的增加而增加;当Fe2+浓度为300 mg/L 时,最大累积产氢量和平均产氢速率最高,分别为302.3 mL和30.0 mL/h .当Fe2+浓度为0~350 mg/L 时,比产氢率随着Fe2+浓度的增加而增加,当Fe2+浓度为350 mg/L 时,最大比产氢率为311.2 mL/g .修正的Logistic模型能很好地描述累积产氢量随时间的变化规律.修正的Han-Levenspiel模型能很好地描述Fe2+浓度对平均产氢速率的影响.
英文摘要
      The effect of Fe2+ concentration ranging from 0 to 1?500 mg/L on the kinetics of fermentative hydrogen production by mixed microbial culture was investigated. The results showed that, at 35℃ and initial pH 7.0, using glucose as substrate, hydrogen production potential and average hydrogen production rate increased with increasing Fe2+concentration from 0 to 300 mg/L , with the maximum hydrogen production potential of 302.3 mL and maximum average hydrogen production rate of 30.0 mL/h being obtained at Fe2+ concentration of 300 mg/L . Hydrogen yield increased with increasing Fe 2+ concentration from 0 to 350 mg/L , with the maximum hydrogen yield of 311.2 mL/g glucose being obtained at Fe2+ concentration of 350 mg/L . Modified Logistic model could describe the progress of cumulative hydrogen production in the batch tests successfully. Modified Han-Levenspiel model could describe the effect of Fe2+ concentrations on average hydrogen production rate successfully.

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