痕量硒的示波极谱测定 |
摘要点击 702 全文点击 1195 投稿时间:1993-04-12 |
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中文关键词 硒 对氨基苯磺酸 示波极谱法 |
英文关键词 Se sulfanilic acid oscillopolarography |
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中文摘要 |
在0.60mol/L醋酸-0.0020mol/L对氨基苯磺酸介质中,Se(Ⅳ)-对氨基苯磺酸配合物于-0.63V处产生一敏锐的单扫描示波极谱波.硒含量在0.3-80ng/ml范围内与波高有线性关系,检出限达0.15ng/ml.利用该波测定实际试样中痕量硒,结果较好. |
英文摘要 |
In 0.60mol/L acetic acid medium, the complex of Se (IV) and sulfanilic acid exhibits a sensitive and selective oscillopolarographic wave at-0.63 V vs.SCE.This provides a new oscillopolarographic method for the determination of Se in the range of 0.3-80ng/ml.The detection limit is achieved at 0.15ng/ml.Se in real samples was analysed by this method, with satisfactory results. |